in neat (no solvent) mixing at ambient temp.; (even slight heating causes explosion with inflammation); cooling (ice) and addn. of fluorite (to prevent explosion); detailed description of apparatus and handling given;; condensation with liquid air; fractionate distillation;;
参考文献
Fischer, J.; Jaencker, W.
Angewandte Chemie, 1929 , vol. 42, p. 810 - 811
in neat (no solvent) careful exclusion of moisture; freshly prepared CoF3 (from F2/CoCl2); vac.; shaking; reaction starts at ambient temps.; heating to 120°C (2h); discoloration to light red marks end of reaction;; condensed (liquid air); fractionate distillation (removal of SF6);;
参考文献
Gmelin Handbook: S: MVol.B3, 79, page 1706 - 1708
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Jaenckner, W.
Diss. Breslau T. H. 1933, S. 7
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Luchsinger, W.
Diss. Breslau T. H. (1935) 1936, S. 23
in neat (no solvent) careful exclusion of moisture; freshly prepared CoF3 (from F2/CoCl2); vac.; shaking; reaction starts at ambient temps.; heating to 120°C (2h); discoloration to light red marks end of reaction;; condensed (liquid air); fractionate distillation (removal of SF6);;
N2 in neat (no solvent, gas phase) at 190°C for 12 h, N2 flow 10l/h;
参考文献
Haszeldine, R. N.
Journal of the Chemical Society, 1950 , p. 1966 - 1968
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Gmelin Handbook: F: PerFHalOrg.8, 4, page 152 - 228
