二(三正丁基甲锡烷基)乙炔合成路线 （共 27 条）
反应条件
n-butyllithium in hexane (N2); introducing an C2H2 stream into a soln. of n-BuLi at -20 to -30°C with stirring; after 10 min warming to room temp.; cooling to 0°C; dropwise addn. of (C4H9)3SnCl soln. with stirring; refluxing for 2 h; filtration; fractinated distn. affords (C4H9)3SnC2H; residue proves to be ((C4H9)3Sn)2C2; (119)Sn-NMR, refractive index;
参考文献
Wrackmeyer, Bernd
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1982 , vol. 37, # 12 p. 1524 - 1528
反应条件
in diethyl ether reflux for 10-12 h;
参考文献
Shostakovskii, M. F.; Komarov, N. V.; Guseva, I. S.; Misyunas, V. K.
Doklady Akademii Nauk SSSR, 1964 , vol. 154/159, p. 1037 - 1039
Doklady Akademii Nauk SSSR, 1964 , vol. 158, p. 918 - 921
Full Text Show Details
Gmelin Handbook: Sn: Org.Comp.12, 1.4.1.1.1.5.1, page 36 - 38
反应条件
1: KOH / water 2: diethyl ether View Scheme
参考文献
Sn: Org.Comp.12, 1.4.1.1.1.5.1, page 36 - 38
反应条件
1: NaOH / water 2: diethyl ether View Scheme
参考文献
Sn: Org.Comp.12, 1.4.1.1.1.5.1, page 36 - 38
参考文献
Shostakovskii, M. F.; Mirskov, R. G.; Ivanova, N. P.
Doklady Akademii Nauk SSSR, 1969 , vol. 184/189, p. 47 - 49
Doklady Akademii Nauk SSSR, 1969 , vol. 184, p. 366 - 368
反应条件
in N,N-dimethyl-formamide Sonication; glove box under N2; mixed, ultrasonication at 25+/-5°C for 120h; centrifuged, washed (pentane or hexane), extd. (three times with pentane or hexane), evapd., distn.;
参考文献
Cochran, John C.; Lemieux, Robert P.; Giacobbe, Robert C.; Roitstein, Alexander
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1990 , vol. 20, p. 251 - 262
反应条件
in N,N-dimethyl-formamide Sonication; glove box under N2; mixed, ultrasonication at 25+/-5°C for 120h; centrifuged, washed (pentane or hexane), extd. (three times with pentane or hexane), evapd., distn.; elem. anal.;
参考文献
Cochran, John C.; Lemieux, Robert P.; Giacobbe, Robert C.; Roitstein, Alexander
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1990 , vol. 20, p. 251 - 262
反应条件
2: diethyl ether View Scheme
参考文献
Sn: Org.Comp.12, 1.4.1.1.1.5.1, page 36 - 38
参考文献
Sn: Org.Comp.12, 1.4.1.1.1.5.2.1.1, page 38 - 56
参考文献
Sn: Org.Comp.12, 1.4.1.1.1.5.2.1.1, page 38 - 56
