2,4,6-三苯基环硼氮六烷合成路线 （共 17 条）
反应条件
1,1,1,3,3,3-hexamethyl-disilazane in dichloromethane
T=55°C; 240 h;
参考文献
Noeth, Heinrich; Troll, Alexander
European Journal of Inorganic Chemistry, 2005 , # 17 p. 3534 - 3535
反应条件
phenylmagnesiumhalide;
参考文献
Haworth; Hohnstedt
Journal of the American Chemical Society, 1960 , vol. 82, p. 3860
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Gmelin Handbook: B: B-Verb.4, 13.3.2, page 329 - 333
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Goldsmith, H.; Woods, W. G.
Patent: FR1321257 , 1963 ;
C.A., 1963 , vol. 59, p. 11557
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Goldsmith, H.
Patent: US3031502 , 1962 ;
C.A., 1963 , vol. 58, p. 5723
反应条件
in dichloromethane
(Ar), (Me3Si)2NH in CH2Cl2 cooled to -78°C, treated with PhBCl2 under stirring, kept at 55°C for 10 d; evapd.(vac.), crystd.(Et2O);
参考文献
Noeth, Heinrich; Troll, Alexander
European Journal of Inorganic Chemistry, 2005 , # 17 p. 3534 - 3535
反应条件
in toluene
byproducts: (CH3)3SiCl;
参考文献
Gmelin Handbook: B: B-Verb.4, 10, page 282 - 288
反应条件
sulfuric acid in sulfuric acid
addn. of 0.3percent concd. H2SO4 to a mixt. of the borate (0.05 mol) and the silazane (0.05 mol); refluxing for 11 h with continuous Ar flushing;; the ppt. was filtered off and recrystd. from hexane; elem. anal.;;
参考文献
Svatikov, M. Yu.; Gruzinova, E. A.; Kotrelev, G. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 7.2 p. 1494 - 1496
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , # 7 p. 1683 - 1685
参考文献
Gmelin Handbook: B: B-Verb.9, 5.2.4, page 189 - 199
反应条件
sulfuric acid in sulfuric acid
byproducts: (CH3)3SiOCH2CH2CH2CH3; addn. of 0.3percent concd. H2SO4 to a mixt. of the borate (0.05 mol) and the silazane (0.1 mol); refluxing for 15 h with continuous Ar flushing;; mixt. not separated, total yield: 48percent;;
参考文献
Svatikov, M. Yu.; Gruzinova, E. A.; Kotrelev, G. V.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1991 , vol. 40, # 7.2 p. 1494 - 1496
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1991 , # 7 p. 1683 - 1685
反应条件
in potassium hydroxide
byproducts: CH4, C6H6; heating 0.01mol phenylboric anhydride and 0.01mol cyclotrisilazane and 0.05g (1percent) KOH for 4h at 180-280°C; analysis of liquid and gaseous products by GLC; extractn. of residue with C6H6, removal of solvent, recrystn. of triphenylborazine from heptane, elem. anal.;
参考文献
Gruzinova, E. A.; Svatikov, M. Yu.; Kotrelev, G. V.; Zhdanov, A. A.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1987 , vol. 36, p. 1059 - 1060
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1987 , vol. 36, p. 1145 - 1146
参考文献
Jenne, H.; Niedenzu, K,.
Inorganic Chemistry, 1964 , vol. 3, p. 68 - 70
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Noeth, H.
Zeitschrift fuer Naturforschung, 1961 , vol. 16b, p. 618 - 620
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Noeth, H.
Angewandte Chemie, 1960 , vol. 72, p. 638 - 638
参考文献
Gmelin Handbook: B: B-Verb.9, 5.2.4, page 189 - 199
