4,4''-二甲基-1,1':4',1''-三联苯合成路线 （共 42 条）
反应条件
C36H32ClN4NiP in tetrahydrofuran
T=70°C; Kumada Cross-Coupling; 20 h; Schlenk techniqueInert atmosphere; Reagent/catalyst;
参考文献
Zhang, Xue-Qi; Wang, Zhong-Xia
Synlett, 2013 , vol. 24, # 16 art. no. ST-2013-W0528-L, p. 2081 - 2084
反应条件
Pd black; potassium carbonate in methanol; acetonitrile
T=20°C; Suzuki Coupling; 2.5 h;
参考文献
Mandali, Pavan Kumar; Chand, Dillip Kumar
Catalysis Communications, 2013 , vol. 31, p. 16 - 20
反应条件
Ni(Cl){2-(Ph2P)C6H4NCH(Ph)P(O)Ph2} in tetrahydrofuran; 1-methyl-pyrrolidin-2-one
T=25°C; Negishi coupling reaction; 24 h; Inert atmosphere;
参考文献
Liu, Ning; Wang, Li; Wang, Zhong-Xia
Chemical Communications, 2011 , vol. 47, # 5 p. 1598 - 1600
反应条件
NiF2; 1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride in tetrahydrofuran
T=60°C; 1 h; Inert atmosphere;
参考文献
Hatakeyama, Takuji; Hashimoto, Sigma; Ishizuka, Kentaro; Nakamura, Masaharu
Journal of the American Chemical Society, 2009 , vol. 131, # 33 p. 11949 - 11963
反应条件
CoF2*4H2O; ethylmagnesium bromide; 1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride in tetrahydrofuran
T=60°C; Inert atmosphere;
参考文献
Hatakeyama, Takuji; Hashimoto, Sigma; Ishizuka, Kentaro; Nakamura, Masaharu
Journal of the American Chemical Society, 2009 , vol. 131, # 33 p. 11949 - 11963
反应条件
potassium carbonate; palladium dichloride in pyridine
Suzuki cross-coupling; 3 h; Heating;
参考文献
Tao, Xiaochun; Zhao, Yinyan; Shen, Dong
Synlett, 2004 , # 2 p. 359 - 361
反应条件
NiCl2[(4-MeOPh)3P]2; K3PO4*3H2O; tris(4-methoxyphenyl)-phosphine in toluene
T=110°C; 10 h; Inert atmosphere;
参考文献
Chen, Xiaofeng; Ke, Haihua; Zou, Gang
ACS Catalysis, 2014 , vol. 4, # 2 p. 379 - 385
反应条件
2,6-di-tert-butyl-4-methyl-phenol; triphenylphosphine; lithium chloride; bis-triphenylphosphine-palladium(II) chloride; copper(I) bromide in N,N-dimethyl-formamide
Heating;
参考文献
Saa, Jose M.; Martorell, Gabriel
Journal of Organic Chemistry, 1993 , vol. 58, # 7 p. 1963 - 1966
反应条件
2,6-di-tert-butyl-4-methyl-phenol; triphenylphosphine; lithium chloride; tetrakis(triphenylphosphine) palladium(0); copper(I) bromide in 1,4-dioxane
Heating;
参考文献
Saa, Jose M.; Martorell, Gabriel
Journal of Organic Chemistry, 1993 , vol. 58, # 7 p. 1963 - 1966
反应条件
C16H16Cl2CoN8(1+)*F6P(1-) in tetrahydrofuran
T=20°C; Kumada-Corriu cross-coupling reaction; 2 h;
参考文献
Xi, Zhenxing; Liu, Bin; Lu, Chunxin; Chen, Wanzhi
Dalton Transactions, 2009 , # 35 p. 7008 - 7014
