1,2,4,5-四氯苯合成路线 （共 206 条）
反应条件
tetrabutylammomium bromide in N,N-dimethyl-formamide T=-5 - 0°C; Dehalogenation; Carboxylation; Electrochemical reaction; Further byproducts given;
参考文献
Collection of Czechoslovak Chemical Communications, , vol. 65, # 6 p. 862 - 880
反应条件
pyridine; [(FeCp)2(1,2,3,4,5,6,7,8,9-nanomethylfluorene)H][PF6]2 in diethylene glycol dimethyl ether T=125°C; Product distribution; Further Variations:reaction times;
参考文献
Fletcher, Andrew E. D.; Moss, James; Cowley, Andrew R.; O'Hare, Dermot
Chemical Communications, 2007 , # 28 p. 2971 - 2973
反应条件
1: NaAlH2(OCH2CH2OCH3)2 / toluene / 70 °C / relative reactivity in dehalogenation; reaction order 2: NaAlH2(OCH2CH2OCH3)2 / toluene / 70 °C / relative reactivity in dehalogenation 3: NaAlH2(OCH2CH2OCH3)2 / toluene / 70 °C / relative reactivity in dehalogenation View Scheme
参考文献
Trukhin; Adonin; Starichenko
Russian Journal of Organic Chemistry, 2000 , vol. 36, # 8 p. 1227 - 1228
反应条件
in methanol electroreduction at a lead cathode;
参考文献
Petersen, Dirk; Lemmrich, Martina; Altrogge, Matthias; Voss, Juergen
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1990 , vol. 45, # 7 p. 1105 - 1107
反应条件
1: iodyl sulfate, conc. H2SO4, fuming H2SO4 (25percent), fuming HNO3 / 3 h / 50 °C
2: 52 percent / sodium hydroxide / H2O / 2 h
View Scheme
参考文献
Nevalainen, Tapio; Rissanen, Kari
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1994 , # 2 p. 271 - 280
反应条件
in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=100°C; 1 h;
参考文献
Testaferri, Lorenzo; Tingoli, Marco; Tiecco, Marcello
Journal of Organic Chemistry, 1980 , vol. 45, # 22 p. 4376 - 4380
反应条件
aluminium trichloride
Ambient temperature;
参考文献
Castaner, J.; Riera, J.; Carilla, J.; Robert, A.; Molins, E.; Miravitlles, C.
Journal of Organic Chemistry, 1991 , vol. 56, # 1 p. 103 - 110
反应条件
1: methanol. NaOH / 160 °C
2: NaOH
3: HNO3 / 5 - 10 °C
4: acetic acid; aqueous ethanol; iron
5: pyridine
6: nitric acid
7: sulfuric acid
View Scheme
参考文献
Harrison; Peters; Rowe
Journal of the Chemical Society, 1943 , p. 235
反应条件
oleum; iodine
T=60°C; 3.5 h;
参考文献
Jabbari, Fatemeh; Saednya, Akbar
Synthesis, 2010 , # 3 p. 395 - 397
反应条件
sodium hydroxide
T=170 - 180°C;
参考文献
Agfa
Patent: DE411052 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 15, p. 194
