bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I); dtbpy in hexane
T=60°C; 4 h;
参考文献
Paul, Sulagna; Chotana, Ghayoor A.; Holmes, Daniel; Reichle, Rebecca C.; Maleczka Jr., Robert E.; Smith III, Milton R.
Journal of the American Chemical Society, 2006 , vol. 128, # 49 p. 15552 - 15553
1.1: phosphorus oxychloride / 2 h / 5 - 20 °C
1.2: 90 percent / potassium hydroxide / H2O
2.1: 80 percent / NaH / dimethylsulfoxide / 2 h / 20 °C
View Scheme
参考文献
Na, Young-Min; Le Borgne, Marc; Pagniez, Fabrice; Le Baut, Guillaume; Le Pape, Patrice
European Journal of Medicinal Chemistry, 2003 , vol. 38, # 1 p. 75 - 87
1.1: phosphorus oxychloride / 2 h / 5 - 20 °C
1.2: 90 percent / potassium hydroxide / H2O
2.1: 80 percent / NaH / dimethylsulfoxide / 2 h / 20 °C
View Scheme
参考文献
Na, Young-Min; Le Borgne, Marc; Pagniez, Fabrice; Le Baut, Guillaume; Le Pape, Patrice
European Journal of Medicinal Chemistry, 2003 , vol. 38, # 1 p. 75 - 87
1.1: trichlorophosphate / 2.5 h / Cooling with ice
1.2: 3 h / 5 °C
1.3: 1 h / Cooling with ice; Reflux
2.1: potassium carbonate / acetone / 24 h / Reflux
View Scheme
参考文献
Moody, Christopher J.; Ward, John G.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 12 p. 2895 - 2901
