1: benzo[b]thiophene With tert.-butyl lithium in tetrahydrofuran; pentane T=-78°C; 0.5 h; Inert atmosphere; 2: benzyl bromide in tetrahydrofuran; pentane T=-78 - 20°C; Inert atmosphere;
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Urban, Slawomir; Beiring, Bernhard; Ortega, Nuria; Paul, Daniel; Glorius, Frank
Journal of the American Chemical Society, 2012 , vol. 134, # 37 p. 15241 - 15244
K10-ZnCl2 in nitromethane T=20°C; 0.5 h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Clark, Peter D.; Kirk, Andrew; Mesher, Shaun T.; Yee, James G.K.
Phosphorus, Sulfur and Silicon and the Related Elements, 1994 , vol. 96, # 1-4 p. 441 - 444
hydrogen; aluminum oxide; cobalt molybdenum P=75005.9 Torr; effect of reaction temperature; degree of conversion as a function of reaction temperature (further catalysts: NiMo/Al2O3, NiW/Al2O3); Product distributionMechanism;
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Schulz, Hans; Do, Dac-Vong
Bulletin des Societes Chimiques Belges, 1984 , vol. 93, # 8-9 p. 645 - 652
