2,2,2-三甲基苯乙酮合成路线 （共 203 条）
反应条件
C10H16NO5; potassium carbonate; bis-[(trifluoroacetoxy)iodo]benzene in dichloromethane T=20°C;
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 31 p. 8093 - 8097
Angew. Chem., , vol. 125, # 31 p. 8251 - 8255,5
反应条件
C10H16NO5; potassium carbonate; bis-[(trifluoroacetoxy)iodo]benzene in dichloromethane T=20°C;
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 31 p. 8093 - 8097
Angew. Chem., , vol. 125, # 31 p. 8251 - 8255,5
反应条件
C10H16NO5; potassium carbonate; bis-[(trifluoroacetoxy)iodo]benzene in dichloromethane T=20°C;
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 31 p. 8093 - 8097
Angew. Chem., , vol. 125, # 31 p. 8251 - 8255,5
反应条件
toluene T=120°C; anschliessend Behandeln mit Eis und NH4Cl und Kochen des Reaktionsprodukts mit konz. wss. Salzsaeure;
参考文献
Bulletin de la Societe Chimique de France, , vol. <5> 2, p. 867,881
Annales de Chimie (Cachan, France), , vol. <12> 1, p. 342,387
Bulletin de la Societe Chimique de France, , p. 1011,1012
反应条件
in diethyl ether 3 h; 0 deg C -> room temperature;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2392 - 2397
反应条件
1: 41 percent / (CF3CO)2O; H2O2 / CH2Cl2 / -20 °C 2: 32 percent / 2,3-dimethyl-1,3-butadiene / CDCl3 / 29 h / Heating View Scheme
参考文献
Tetrahedron Letters, , vol. 42, # 17 p. 3117 - 3119
反应条件
1: 22 percent / LDA / tetrahydrofuran / 1.) -78 deg C, 15 min; 2.) warm up to RT, 1 h 2: 38 percent / 650 °C / 0.01 Torr View Scheme
参考文献
Synlett, , vol. 1997, # 3 p. 293 - 294
反应条件
1.1: copper(l) iodide; caesium carbonate / N,N-dimethyl-formamide / 24 h / 135 °C / |Inert atmosphere; |Sealed tube 2.1: methyllithium / tetrahydrofuran; diethyl ether; pentane / 20 h / 0 - 20 °C / |Inert atmosphere 2.2: 1 h / 20 °C / |Inert atmosphere 3.1: ruthenium(II)-carbonyl-tris(triphenylphosphine) dihydride / para-xylene / 24 h / 140 °C / |Schlenk technique; |Glovebox; |Inert atmosphere View Scheme
参考文献
Journal of Organometallic Chemistry, , vol. 741-742, # 1 p. 148 - 152
反应条件
1.1: methyllithium / tetrahydrofuran; diethyl ether; pentane / 20 h / 0 - 20 °C / |Inert atmosphere 1.2: 1 h / 20 °C / |Inert atmosphere 2.1: ruthenium(II)-carbonyl-tris(triphenylphosphine) dihydride / para-xylene / 24 h / 140 °C / |Schlenk technique; |Glovebox; |Inert atmosphere View Scheme
参考文献
Journal of Organometallic Chemistry, , vol. 741-742, # 1 p. 148 - 152
反应条件
in tetrahydrofuran; diethyl ether 4 h; Ambient temperature;
参考文献
Indian Journal of Chemistry - Section B Organic Chemistry Including Medicinal Chemistry, , vol. 30, # 2 p. 250 - 255
