1-(2-甲基苯基)-3-苯基-1-丙酮合成路线 （共 14 条）
反应条件
1: 3-phenylpropionic acid With N,N'-disuccinimidyl-carbonate; sodium carbonate; tri-cyclo-hexyl-phosphine; Pd(F6-acac)2 in tetrahydrofuran
T=60°C;
2: (2-methylphenyl)boronic acid in tetrahydrofuran
T=60°C; 20 h; Further stages.;
参考文献
Goossen; Ghosh
Chemical Communications, 2001 , # 20 p. 2084 - 2085
反应条件
potassium hydroxide; dodec-1-ene; tris(triphenylphosphine)ruthenium(II) chloride in 1,4-dioxane
T=80°C; 20 h;
参考文献
Cho, Chan Sik; Kim, Bok Tae; Kim, Tae-Jeong; Chul Shim, Sang
Tetrahedron Letters, 2002 , vol. 43, # 44 p. 7987 - 7989
反应条件
tri-n-butyltin methoxide; bis (triortho-tolylphosphine)palladium(II) chloride in dimethyl sulfoxide
T=100°C; 14 h;
参考文献
Jean, Mickael; Renaulty, Jacques; Uriac, Philippe; Capet, Marc; Van De Weghe, Pierre
Organic Letters, 2007 , vol. 9, # 18 p. 3623 - 3625
反应条件
carbon monoxide
T=150°C; Friedel-Crafts acylation; P=15201 Torr; 30 h;
参考文献
Ogoshi; Nakashima; Shimonaka; Kurosawa
Journal of the American Chemical Society, 2001 , vol. 123, # 35 p. 8626 - 8627
反应条件
potassium hydroxide; tris(triphenylphosphine)ruthenium(II) chloride in 1,4-dioxane
T=80°C; 40 h;
参考文献
Cho, Chan Sik; Shim, Sang Chul
Journal of Organometallic Chemistry, 2006 , vol. 691, # 20 p. 4329 - 4332
反应条件
lithium n-butyldiisobutylaluminum hydride; (2,6-t-Bu2-4-Me-C6H2O)2AlMe in diethyl ether; hexane; toluene
T=-78°C; 0.25 h;
参考文献
Nonoshita, Katsumasa; Maruoka, Keiji; Yamamoto, Hisashi
Bulletin of the Chemical Society of Japan, 1988 , vol. 61, p. 2241 - 2243
反应条件
tris(triphenylphosphine)ruthenium(II) chloride; potassium hydroxide in 1,4-dioxane
T=80°C; 40 h;
参考文献
Cho, Chan Sik; Kim, Bok Tae; Yoon, Nam Sik
Applied Organometallic Chemistry, 2011 , vol. 25, # 9 p. 695 - 698
反应条件
tris(triphenylphosphine)ruthenium(II) chloride; dodec-1-ene; potassium hydroxide in 1,4-dioxane
T=80°C; 40 h;
参考文献
Cho, Chan Sik; Kim, Bok Tae; Yoon, Nam Sik
Applied Organometallic Chemistry, 2011 , vol. 25, # 9 p. 695 - 698
反应条件
N-benzyl-N,N,N-triethylammonium chloride; palladium diacetate; sodium hydrogencarbonate in acetonitrile
T=50°C; Mizoroki-Heck reaction; 1.5 h; Inert atmosphereMicrowave irradiation; regioselective reaction;
参考文献
Krishna; Reddy, A. Gopi Krishna; Ramulu, B. Venkat; Mahendar; Satyanarayana
Synlett, 2012 , # 3 p. 375 - 380
反应条件
benzene
Erhitzen des Reaktionsprodukts mit Toluol-4-sulfonsaeure, Essigsaeure und wenig Acetanhydrid;
参考文献
Fonken; Johnson
Journal of the American Chemical Society, 1952 , vol. 74, p. 831
