5-乙基-3,5-二甲基苯合成路线 （共 25 条）
反应条件
1: ammonia / 350 °C / 117681 - 183877 Torr
2: ueber die Diazonium-Verbindung
3: diethyl ether / anschliessend Erwaermen mit verd. wss. Schwefelsaeure
4: amalgamated zinc; aqueous HCl
View Scheme
参考文献
Birch et al.
Journal of the American Chemical Society, 1949 , vol. 71, p. 1362,1366
反应条件
1: 93 percent / SOCl2
2: 86 percent / CdCl2 / benzene / 1 h / Heating
3: 82 percent / H2N-NH2*H2O, KOH
View Scheme
参考文献
Fuchs, Bernhard; Froehlich, Roland; Musso, Hans
Chemische Berichte, 1985 , vol. 118, # 5 p. 1968 - 1982
反应条件
1: 86 percent / CdCl2 / benzene / 1 h / Heating
2: 82 percent / H2N-NH2*H2O, KOH
View Scheme
参考文献
Fuchs, Bernhard; Froehlich, Roland; Musso, Hans
Chemische Berichte, 1985 , vol. 118, # 5 p. 1968 - 1982
反应条件
aluminium trichloride
T=40°C;
参考文献
Stahl
Chemische Berichte, 1890 , vol. 23, p. 990
反应条件
diethyl ether; sodium
参考文献
Wroblewski
Justus Liebigs Annalen der Chemie, 1878 , vol. 192, p. 210
反应条件
1: AlCl3
2: AlCl3
View Scheme
参考文献
Kunckell; Ulex
Journal fuer Praktische Chemie (Leipzig), 1913 , vol. <2> 87, p. 232
反应条件
aluminium trichloride
参考文献
Kunckell; Ulex
Journal fuer Praktische Chemie (Leipzig), 1913 , vol. <2> 87, p. 232
参考文献
Jacobsen
Chemische Berichte, 1874 , vol. 7, p. 1433
反应条件
phosphoric acid
T=220°C; 3 h; AutoclaveInert atmosphere; Temperature;
参考文献
Kang, Shimin; Yu, Jian
RSC Advances, 2014 , vol. 4, # 28 p. 14320 - 14327
反应条件
T=100°C; 0.58 h; Further byproducts given;
参考文献
Booth, Brian L.; Haszeldine, Robert N.; Laali, Khosrow
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 2887 - 2893
