1: With 3-chloro-benzenecarboperoxoic acid in dichloromethane T=20°C; Baeyer-Villiger Ketone Oxidation; 2: With triethylamine in dichloromethane T=20°C; 0.5 h;
参考文献
Fink, Michael J.; Rial, Daniela V.; Kapitanova, Petra; Lengar, Alenka; Rehdorf, Jessica; Cheng, Qiong; Rudroff, Florian; Mihovilovic, Marko D.
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 18 p. 3491 - 3500
1: cycloheptanone With n-butyllithium; diisopropylamine in tetrahydrofuran; hexane
T=-78°C; 1.5 h;
2: methyl iodide in tetrahydrofuran; hexane
T=20°C; 15 h;
参考文献
Fuerstner, Alois; Albert, Martin; Mlynarski, Jacek; Matheu, Maribel; DeClercq, Erik
Journal of the American Chemical Society, 2003 , vol. 125, # 43 p. 13132 - 13142
