fructose-derived ketone; potassium carbonate in acetonitrile T=0°C; Oxidation; 2 h; Title compound not separated from byproducts;

暂无反应条件数据

暂无反应条件数据

1.1: 85 percent / triethylamine; thionyl chloride / 0.75 h / 0 °C 2.1: sodium azide / dimethylformamide / 6 h / 80 °C 2.2: PPh3 / acetonitrile / 6 h / Heating 2.3: ammonium formate / Pd/C / methanol / 4 h / Heating 3.1: aq. K2CO3 / CH2Cl2 / 0.75 h 4.1: 0.215 g / LiAlH4 / tetrahydrofuran / 2 h / Heating 5.1: K2CO3 / acetonitrile / 20 °C View Scheme

1.1: 85 percent / triethylamine; thionyl chloride / 0.75 h / 0 °C 2.1: sodium azide / dimethylformamide / 6 h / 80 °C 2.2: PPh3 / acetonitrile / 6 h / Heating 2.3: ammonium formate / Pd/C / methanol / 4 h / Heating 3.1: aq. K2CO3 / CH2Cl2 / 0.75 h 4.1: 0.215 g / LiAlH4 / tetrahydrofuran / 2 h / Heating View Scheme

1.1: 85 percent / triethylamine; thionyl chloride / 0.75 h / 0 °C 2.1: sodium azide / dimethylformamide / 6 h / 80 °C 2.2: PPh3 / acetonitrile / 6 h / Heating 2.3: ammonium formate / Pd/C / methanol / 4 h / Heating 3.1: aq. K2CO3 / CH2Cl2 / 0.75 h 4.1: 0.215 g / LiAlH4 / tetrahydrofuran / 2 h / Heating 5.1: K2CO3 / acetonitrile / 20 °C View Scheme