2-(1-甲基丁基)苯酚合成路线 （共 12 条）
反应条件
aluminium trichloride
T=40 - 50°C;
参考文献
Zukerwanik; Nasarowa
Zhurnal Obshchei Khimii, 1937 , vol. 7, p. 623,629
Chem. Zentralbl., 1937 , vol. 108, # II p. 1363
反应条件
7-phenyl-5,6,8,9-tetrahydrodibenzolt;c,hgt;xanthylium trifluoromethanesulphonate; triethylamine
T=25°C; 72 h; Title compound not separated from byproducts;
参考文献
Katritzky, Alan R.; Lopez-Rodriguez, Maria L.; Keay, James G.; King, Roy W.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1985 , p. 165 - 170
反应条件
hydrogen iodide; phenol
参考文献
Dutton,G.G.S. et al.
Canadian Journal of Chemistry, 1964 , vol. 42, p. 480 - 482
反应条件
1: (dehydration)
2: (hydrogenation)
3: aq. HI, PhOH
View Scheme
参考文献
Dutton,G.G.S. et al.
Canadian Journal of Chemistry, 1964 , vol. 42, p. 480 - 482
反应条件
1: (hydrogenation)
2: aq. HI, PhOH
View Scheme
参考文献
Dutton,G.G.S. et al.
Canadian Journal of Chemistry, 1964 , vol. 42, p. 480 - 482
反应条件
Al(Hal)3
T=169.9°C; 13 h; var. temp., time, ΔrH0m, ΔrS0m; Equilibrium constantThermodynamic data;
参考文献
Nesterova, T. N.; Pimerzin, A. A.; Rozhnov, A. M.; Karlina, T. N.
Journal of Chemical Thermodynamics, 1989 , vol. 21, # 4 p. 385 - 396
反应条件
T=100°C; 48 h; various cation-exchanged montmorillonites; Product distribution;
参考文献
Tateiwa, Jun-Ichi; Hayama, Ei; Nishimura, Takahiro; Uemura, Sakae
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 13 p. 1923 - 1928
反应条件
triethylamine
T=25°C; 72 h; further aromatic compounds; also with 1-ethylpropylamine; Product distributionMechanism;
参考文献
Katritzky, Alan R.; Lopez-Rodriguez, Maria L.; Keay, James G.; King, Roy W.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1985 , p. 165 - 170
反应条件
1: N-chlorosuccinimide (NCS) / CH2Cl2 / 0.5 h / -25 °C
2: triethylamine / CH2Cl2 / 4 h / Ambient temperature
3: W2 Raney nickel / ethanol / 24 h / Heating
View Scheme
参考文献
James, Roger; Glen, John B.
Journal of Medicinal Chemistry, 1980 , vol. 23, # 12 p. 1350 - 1357
反应条件
aluminium
1.) 120 deg C, 2 h, 2.) a) from 40 deg C to 200 deg C, 4 h, b) 200 deg C, 2 h; Yield given. Multistep reaction;
参考文献
James, Roger; Glen, John B.
Journal of Medicinal Chemistry, 1980 , vol. 23, # 12 p. 1350 - 1357
