potassium phosphate; Na2[PdCl4]; sodium lauryl sulfate in water T=100°C; Suzuki coupling; 0.0833333 h;

1: 4-fluoro-1-iodobenzene With [PdCl2(1,3-bis(diphenylphosphino)propane)]; tBuCH2CH2B(H)NiPr2; triethylamine; potassium iodide in toluene T=110°C; Suzuki coupling; 1 h; Inert atmosphere; 2: 1-chloro-3-iodobenzene With caesium carbonate in ethanol; water; toluene T=90°C; Suzuki coupling; 15 h; Inert atmosphere;

potassium phosphate; palladium diacetate in water; N,N-dimethyl-formamide T=20°C; Suzuki-Miyaura cross-coupling; 3 h;

potassium acetate; 18-crown-6 ether 1.5 h; Ambient temperature; Yield given. Yields of byproduct given;

iron(III) trifluoromethanesulfonate; di-tert-butyl peroxide; 4,7-bis[4-(trifluoromethyl)phenyl]-1,10-phenanthroline T=80°C; 24 h;

T=30°C; 20 h; Irradiation; Product distribution;