in tetrahydrofuran byproducts: KCl; (inert conditions); stirring overnight mixt. of cerium compd. and potassium salt in THF; filtration, evapn., extn. (toluene), filtration, evapn., elem. anal.;
参考文献
Evans, William J.; Rego, Daniel B.; Ziller, Joseph W.
Inorganic Chemistry, 2006 , vol. 45, # 26 p. 10790 - 10798
in tetrahydrofuran solvent addn. to Ce-salt under Ar, mixt. stirring briefly, suspn. sonication for 1 h, stirring at room temp. for 18 h, cooling to -78°C, slow org. compd. addn., stirring for 1.5 h at this temp.;
参考文献
Wee, Andrew G. H.; Tang, Fuxing
Canadian Journal of Chemistry, 1998 , vol. 76, # 7 p. 1070 - 1081
in ethanol byproducts: cerium amalgam; alcoholic soln. of water free CeCl3;;
参考文献
West, D. H.; Hopkins, B. S.
Journal of the American Chemical Society, 1935 , vol. 57, p. 2185 - 2186
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Gmelin Handbook: Hg: MVol.A2, 158, page 965 - 967
CeCl3 added to the ternary sulphate eutectic of Li2SO4-Na2SO4-K2SO4 andheated; reaction commenced at 200 and 750°C; product CeO2 identified by X-Ray diffraction, SO2 and SO3 by IR;
参考文献
Al Omer, S. S.; Habboush, D. A.; Isaac, I. Y.
Thermochimica Acta, 1981 , vol. 49, p. 259 - 268
in water
digested; filtering, washed with water, then with alcohol, dried in oven at 110°C, recrystn. from anhydrous benzene;
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Misra, S. N.; Misra, T. N.; Mehrotra, R. C.
Journal of Inorganic and Nuclear Chemistry, 1963 , vol. 25, p. 195 - 199
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Gmelin Handbook: Sc: MVol.D5, 1.1.19, page 88 - 90
in tetrahydrofuran
solvent addn. to Ce-salt under Ar, mixt. stirring briefly, suspn. sonication for 1 h, stirring at room temp. for 18 h, cooling to -78°C, slow org. compd. addn., stirring for 1.5 h at this temp.;
参考文献
Wee, Andrew G. H.; Tang, Fuxing
Canadian Journal of Chemistry, 1998 , vol. 76, # 7 p. 1070 - 1081
in sulfuric acid
Kinetics; Irradiation (UV/VIS); soln. of 2KHSO5*KHSO4*K2SO4 in H2O and CeCl3 in 0.50 M H2SO4 irradiated at 25°C and pH 0.30; not isolated; monitored by UV-vis spectra;