in solid matrix Irradiation (UV/VIS); Photolysis of codeposited O3 and PBr3 in an argon-matrix (successively at 630-1000, 590-1000, 520-1000 and 220-1000 nm for 20 min periods).; High-resolution IR at 1036.9 and 1040.8 1/cm.;
参考文献
Journal of Physical Chemistry, , vol. 93, # 5 p. 1902 - 1907
→
反应条件
in neat (no solvent) reaction at ambient temperature;;
参考文献
Journal of the Chemical Society, , vol. 59, p. 1019 - 1029
in tetrachloromethane reaction of PBr soln. in CCl4 on dropwise added of a soln. of ClO2 in CCl4; pptn. of Br2 and formation of solid PBr5*2CCl4, liquid phase contains POBr3;;
参考文献
Gazzetta Chimica Italiana, , vol. 89, p. 2046 - 2052
