cyclopenta-1,3-diene in methanol Kinetics; byproducts: trans-3,4-dimethoxy-1-cyclopentene, trans-3,5-dimethoxy-1-cyclopentene, cis-3,5-dimethoxy-1-cyclopentene; soln. of cyclopentadiene in MeOH added with stirring to soln. of CuBr2 in MeOH; reacted at 30-50°C for 20-70 min; CuBr, three dimethoxycyclopentene isomers and 3-methoxy-4-bromo-1-cyclopentene obtained;
参考文献
Russian Chemical Bulletin, , vol. 51, # 4 p. 616 - 624
Izvestiya Akademi Nauk, Seriya Khimicheskaya, , # 4 p. 572 - 579
cyclopenta-1,3-diene in ethanol; N,N-dimethyl-formamide Kinetics; soln. of cyclopentadiene in DMF-EtOH added with stirring to soln. of CuBr2 in DMF-EtOH; reacted at 30°C;
参考文献
Russian Chemical Bulletin, , vol. 51, # 4 p. 616 - 624
Izvestiya Akademi Nauk, Seriya Khimicheskaya, , # 4 p. 572 - 579
phenyl silane in acetonitrile hydrosilane was added to a soln. of Cu-salt in acetonitrile, the mixt. was stirred for 30 min; X-ray diffraction;
参考文献
Takahashi, Masaki; Kamada, Jun; Iwata, Kenji; Goto, Kenichi; Watanabe, Hiroshi; Tamai, Shoji
Bulletin of the Chemical Society of Japan, 2008 , vol. 81, # 1 p. 168 - 170
cyclopenta-1,3-diene in N,N-dimethyl-formamide; isopropyl alcohol Kinetics; soln. of cyclopentadiene in DMF-i-PrOH added with stirring to soln. of CuBr2 in DMF-i-PrOH; reacted at 30°C;
参考文献
Russian Chemical Bulletin, , vol. 51, # 4 p. 616 - 624
Izvestiya Akademi Nauk, Seriya Khimicheskaya, , # 4 p. 572 - 579
cyclopenta-1,3-diene in further solvent(s) Kinetics; soln. of cyclopentadiene in DMF-s-BuOH added with stirring to soln. of CuBr2 in DMF-s-BuOH; reacted at 30°C;
参考文献
Russian Chemical Bulletin, , vol. 51, # 4 p. 616 - 624
Izvestiya Akademi Nauk, Seriya Khimicheskaya, , # 4 p. 572 - 579