trifluorophosphane合成路线 （共 187 条）
反应条件
in not given
only formation of a volatile gas;;
参考文献
Finch, A.
Canadian Journal of Chemistry, 1959 , vol. 37, p. 1793 - 1794
Show Details
Gmelin Handbook: P: MVol.C, 169, page 388 - 391
参考文献
Canterford, J. H.; O'Donnel, T. A.
Inorganic Chemistry, 1966 , vol. 5, p. 1442 - 1446
参考文献
Gmelin Handbook: U: SVol.C8, 5.1.5.3, page 139 - 163
反应条件
in neat (no solvent)
参考文献
McIvor, R. W. E.
Ber., 1975 , vol. 8, p. 1466 - 1466
Show Details
Gmelin Handbook: P: MVol.C, 215, page 494 - 496
参考文献
Canterford, J. H.; O'Donnel, T. A.
Inorganic Chemistry, 1966 , vol. 5, p. 1442 - 1446
反应条件
in neat (no solvent)
heating 1 mol P2S5 with 3 mol PbF3 in a leaded autoclave at 170 °C in a stream of N2;; distg. off PCl3 and PCl5;;
参考文献
Voznesenskii, S. A.; Dubnikov, L. M.
Zh. obshch. Khim., 1941 , vol. 11, p. 507 - 517
C. II, 1941 , p. 1721
反应条件
in solid
byproducts: I2; slow decompn. to AsF3, PF3 and I2;
参考文献
Tornieporth-Oetting, Inis; Klapoetke, Thomas
Journal of the Chemical Society, Chemical Communications, 1990 , # 2 p. 132 - 133
反应条件
in not given
room temp.; not isolated, detd. by (31)P-NMR spectroscopy;
参考文献
Cradock,S. et al.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1976 , p. 1661 - 1667
反应条件
in neat (no solvent)
-130 to -78°C; not isolated, detd. by Raman spectroscopy;
参考文献
Chen, Grace S. H.; Passmore, Jack
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1251 - 1256
反应条件
in dichloromethane
Sonication; not isolated, detected by NMR;
参考文献
Koechner, Tobias; Engesser, Tobias A.; Scherer, Harald; Plattner, Dietmar A.; Steffani, Alberto; Krossing, Ingo
Angewandte Chemie - International Edition, 2012 , vol. 51, # 26 p. 6529 - 6531
