trifluorophosphane合成路线 （共 187 条）
反应条件
in tetrahydrofuran under inert atmosphere, react. of PF3 with 3 equiv of L-Selectride in THF at temperature from -100 to 25°C;
参考文献
Moissan, H.
Ann. Chim. Phys., 1885 , vol. 6, p. 433 - 467
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Gmelin Handbook: P: MVol.C, 171, page 393 - 395
反应条件
in neat (no solvent) byproducts: HF; heating with gaseous HCl;;
参考文献
Moissan, H.
Ann. Chim. Phys., 1885 , vol. 6, p. 433 - 467
Full Text Show Details
Gmelin Handbook: P: MVol.C, 171, page 393 - 395
反应条件
in diethyl ether byproducts: LiF, AlF3; LiAlH4 in ether frozen with liq. N2, PF3 introduced in react. vessel, coolant withdrawn, allowed to attain room temp., set aside for 1 h, frozen again, allowed to room temp., left overnight; vessel connected to two bubblers contg. KOH and contg. HgCl2 soln., gaseous product swept off in current of N2, phosphine got absorbed into mercuric chloride soln.;
参考文献
Kalbandkeri, R. G.; Padma, D. K.; Vasudeva Murthy, A. R.
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1984 , vol. 23, p. 875 - 875
反应条件
in not given formation from PF3 by hydrolysis in a bicarbonate buffered system at pH=7;; potentiometric titration;;
参考文献
Gmelin Handbook: P: MVol.C, 176, page 405 - 406
反应条件
copper in not given Cu-powder pre-treated with H2 at 400°C; pot-to pot distn. (-78°C), then distn. through P2O5 or 5A molecular sieves;
参考文献
Hammill, Cynthia L.; Clark, Ronald J.; Ross, Charles W. III; Marshall, Alan G.; Schmutz, James
Inorganic Chemistry, 1997 , vol. 36, p. 5973 - 5977
反应条件
in gas High Pressure; PF3 and SF6 (molar ratio 1.1:1) condences into gold tube at -196°C, sealed, held at 500°C (300 atm) for 24 h; detected by IR spectra;
参考文献
Inorganic Chemistry, , vol. 20, p. 1325 - 1326
反应条件
in gas PF3 and SF4 (molar ratio 1.5:1) sealed in gold tube, heated at 324°C (2133 atm) for 24 h; detected by IR spectra;
参考文献
Inorganic Chemistry, , vol. 20, p. 1325 - 1326
参考文献
Gmelin Handbook: B: MVol., 8.1, page 112 - 113
反应条件
in neat (no solvent) react. of C with PF3 in a Ni-tube at 1100°C;;
参考文献
US2709186 , ;
C. A., , p. 6499
反应条件
in neat (no solvent) reaction at elevated temperatures;;
参考文献
Si: MVol.B, 224, page 614 - 617
Ann. Chim. Phys., , vol. 12, p. 472 - 537
