1-甲基-2,2-二苯基乙烯合成路线 （共 153 条）
反应条件
in diethyl ether; hexane
T=20°C; 1 h; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Tanaka, Jiro; Nojima, Masatomo; Kusabayashi, Shigekazu
Journal of the American Chemical Society, 1987 , vol. 109, # 11 p. 3391 - 3397
反应条件
triethylsilane; boron trifluoride diethyl etherate in dichloromethane
T=0°C; 0.5 h; Yield given. Yields of byproduct given;
参考文献
Orfanopoulos, Michael; Smonou, Ioulia
Synthetic Communications, 1988 , vol. 18, # 8 p. 833 - 840
反应条件
rhodium-carbene-complex in toluene
T=50°C; 6 h;
参考文献
Wolf, Justin; Brandt, Lutz; Fries, Arno; Werner, Helmut
Angewandte Chemie, 1990 , vol. 102, # 5 p. 584 - 586
反应条件
lithium in tetrahydrofuran; diethyl ether; pentane
T=-110 - -80°C; 3 h; Further byproducts given;
参考文献
Maercker, Adalbert; Boes, Benno; Hajgholipour, Mohammad Taghi
Journal of Organometallic Chemistry, 1998 , vol. 566, # 1-2 p. 143 - 149
反应条件
tert.-butyl lithium in tetrahydrofuran; pentane
T=-90 - -70°C; 0.75 h;
参考文献
Maercker, Adalbert; Boes, Benno; Hajgholipour, Mohammad Taghi
Journal of Organometallic Chemistry, 1998 , vol. 566, # 1-2 p. 143 - 149
反应条件
1: 1,1-diphenyl-2-bromoethylene With n-butyllithium; N,N,N',N,-tetramethylethylenediamine in hexane; pentane
T=-100 - 0°C; 0.5 h;
2: dimethyl sulfate in hexane; pentane
T=-90 - 20°C; 4 h;
参考文献
Korneev, Sergei M.; Kaufmann, Dieter E.
Synthesis, 2002 , # 4 p. 491 - 496
反应条件
1.1: tetrahydrofuran; hexane / 1 h / -78 °C
1.2: 90 percent / tetrahydrofuran; hexane / 20 °C
2.1: 82 percent / Fe(acac)3; MeMgI / toluene; diethyl ether / Heating
View Scheme
参考文献
Huang, Li-Fu; Chen, Chih-Wei; Luh, Tien-Yau
Organic Letters, 2007 , vol. 9, # 18 p. 3663 - 3665
参考文献
Lewis; Wright
Journal of the American Chemical Society, 1952 , vol. 74, p. 1257
反应条件
in tetrahydrofuran
T=-45°C;
参考文献
Huisgen, Rolf; Xingya, Li
Heterocycles, 1983 , vol. 20, # 12 p. 2363 - 2368
反应条件
in benzene-d6
T=20°C; 2 h;
参考文献
Werner, Helmut; Schwab, Peter; Bleuel, Elke; Mahr, Norbert; Windmueller, Bettina; Wolf, Justin
Chemistry - A European Journal, 2000 , vol. 6, # 24 p. 4461 - 4470
