phosphate buffer; NaClO4 in water Kinetics; oxidn. of NaClO2 by HOCl in distd. water in the presence of phosphate buffer; 25°C; ionic strength 1.0 M (NaClO4); pH 5.0-8.0; rate constant depended on ClO2(1-) concn., pH, buffer concn.; not isolated;
参考文献
Jia, Zhongjiang; Margerum, Dale W.; Francisco, Joseph S.
Inorganic Chemistry, 2000 , vol. 39, # 12 p. 2614 - 2620
hydrogen cation in water Kinetics; byproducts: H2O; KMnO4 was reacted with NaClO2 in aq. acid at 25°C, pH 1.1-5.00, ionic strength 0.016-2.18 M (NaClO4); monitored spectrophotometrically;
参考文献
Ahlstrom, Christine; Boyd, Donald W.; Epstein, Irving R.; Kustin, Kenneth; Romanow, John H.
Inorganic Chemistry, 1984 , vol. 23, p. 2185 - 2188
Prokopcikas, A.; Butkevicius, J.
Lietuvos TSR Mokslu Akad. Darbai B, 1962 , # 3 p. 95 - 107
C. A., 1963 , vol. 58, p. 6439
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Gmelin Handbook: Cl: SVol.B2, 40, page 402 - 404
sodium perchlorate in water Kinetics; react. of ozone with NaClO2 (2-10-fold excess) in aq. soln. at 25.0°C, pH 6.00, ionic strength 1.0 M (NaClO4); monitored by stopped-flow spectroscopy;
参考文献
Nicoson, Jeffrey S.; Wang, Lu; Becker, Robert H.; Hartz, Kara E. Huff; Muller, Charles E.; Margerum, Dale W.
Inorganic Chemistry, 2002 , vol. 41, # 11 p. 2975 - 2980
