ammonia in water
the reaction is faster in the presence of PtPd, Pd/H2 or Zn; the formation of NH4NO2 is faster in hot soln. in the presence of NaOH or Na2CO3;
参考文献
Schoenbein, C. F.
Journal fuer Praktische Chemie (Leipzig), 1858 , vol. 75, p. 99
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Weith,; Weber, A.
Ber., 1874 , vol. 7, p. 1745
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Gmelin Handbook: NH4: MVol.1, 1.5, page 12 - 20
in water
equal vols. of Na2S2O3 aq. soln. (concn. of 100.0 μmol dm**-3) and H2O2 aq. soln. (concn. of 2.00 mmol dm**-3) mixed well; react. run at 25 °C and pH 6 for >5000 min; SO4(2-) determined by ion chromy.; S3O6(2-) and S4O6(2-) determined by HPLC with UV-visible detector;
参考文献
Sato, Keiichi; Furuya, Satoshi; Takenaka, Norimichi; Bandow, Hiroshi; Maeda, Yasuaki; Furukawa, Yoshinori
Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 6 p. 1139 - 1144
