in water
hydrolysis; heat of react. investigated;;
参考文献
Charney, I.; Skinner, H. A.
Journal of the Chemical Society, 1953 , p. 450 - 452
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Gmelin Handbook: P: MVol.C, 183, page 421 - 424
in neat (no solvent)
byproducts: pyrophosphite, diphosphate; mixing PCl3 with anhydrous H3PO4 and H3PO3 (molar ratio of educts 1:3:2); heating at 50 °C for 10 h; neutralization;; formation of a large amount of iso-hypophosphate (Na3HP2O6) and diphosphate (Na2H2P2O7) and a small amount of pyrophosphite (Na2H2P2O5); detected by iodometry and chromatography;;
参考文献
Thilo, E.; Heinz, D.
Z. anorg. allg. Chem., 1955 , vol. 281, p. 303 - 321
in not given
byproducts: P; react. with H3PO4 at water bath temp. forming HPO3, H3PO3 and HCl; react. of H3PO3 with PCl3 forming P, H3PO4 and HCl; react. of HPO3 with H3PO4 forming H4P2O7 and decompn. of H4P2O7 with PCl3 on heating forming HPO3, H3PO3 and HCl;;
参考文献
Geuther, A.
Jenaische Z. Med. Nturwiss., 1873 , vol. 7, p. 380 - 390
