indium(III) chloride; chloro-trimethyl-silane in dichloromethane
0 deg C to RT;
参考文献
Mukaiyama, Teruaki; Ohno, Takashi; Nishimura, Takashi; Han, Jeong Sik; Kobayashi, Shu
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 8 p. 2524 - 2527
1: 93 percent / dimethylformamide / 3 h / Ambient temperature
2: 81 percent / piperidine, DBU / acetonitrile / 5 h / Ambient temperature
View Scheme
参考文献
Yamada, Hiroyuki; Kinoshita, Hideki; Inomata, Katsuhiko; Kotake, Hiroshi
Bulletin of the Chemical Society of Japan, 1983 , vol. 56, # 3 p. 949 - 950
→
反应条件
in toluene
soln. of Ti complex treated with PhCH2Br, refluxed with stirring under N2 for 4.5 h; evapn. to dryness (rotatory evaporator) upon cooling, extn. (hexanes), filtration (insol. Cp2TiBr2), evapn. of the filtrate;