CH3MgBr in diethyl ether; pentane; benzene byproducts: tetraphenylnaphthalene; Norbornadiene-compound and allyl bromide are heated at 25°C for 4 h in benzene, after distilling of volatiles the residue is stirred in pentane at room temp. for 1.5 h, then methylation (MeMgBr in Et2O, 0°C (0.5 h), room temp. (1 h)) (Ar).; pptn. of tetraphenylnaphthalene, the mixture containing ether, benzene and CH2CHCH2GeMe3 is separated by distilling in vac. at room temp. and collecting in a trap cooled with dry ice, removal of ether by using a microcolumn, detected by (1)H NMR, GC-MS;

CH3MgCl in diethyl ether; benzene Norbornadiene-compound and allyl chloride are heated at 70°C for 4 h in benzene, followed by methylation with MeMgCl in Et2O (stirring of reaction mixture at 0°C for 0.5 h, then stirring at room temp. for 1 h) (Ar).; All volatile compounds are separated by distilling in vac. at room temp. and collecting in a trap cooled with dry ice, removal of ether, residue contains traces of ether and benzene, detected by (1)H NMR and GC-MS.;

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Tl(OCOCF3)3 in dichloromethane 0.5 h; Ambient temperature; Yield given. Yields of byproduct given;

diethyl ether; iodosylbenzene; boron trifluoride 1 h; Ambient temperature;

catalyst: Re2O7/Al2O3-SnBu4 or Re2O7/Al2O3-PbEt4 in not given byproducts: ethylene; under Ar, react. of the vapors of boiling substrate and solvent at the catalysts;

phenylthalium(III) di(trifluoroacetate) 2.5 h; Ambient temperaturevariation of ratio of reactants; Product distribution;

Tl(OCOCF3)3 in dichloromethane 0.5 h; Ambient temperature; Yield given. Yields of byproduct given;

Tl(NO3)3*3H2O in 1,4-dioxane 0.166667 h; Ambient temperature;

in acetonitrile Irradiation; Quantum yield;