顺式-1.1.1-三甲基-2-丁烯合成路线 （共 13 条）
反应条件
methanol; sodium hydroxide; diisopinocamphenylboron chloride; dihydrogen peroxide 1.) a.) THF, -25 deg C, 48 h, b.) 0 deg C, 24 h, 2.) 55 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Brown, Herbert C.; Desai, Manoj C.; Jadhav, Prabhakar K.
Journal of Organic Chemistry, 1982 , vol. 47, # 26 p. 5065 - 5069
反应条件
WH(η5-C5HMe4)(CO3) in benzene-d6 T=140°C; 48 h;
参考文献
Chahboun, Ghaita; Petrisor, Cristina E.; Gomez-Bengoa, Enrique; Royo, Eva; Cuenca, Tomas
European Journal of Inorganic Chemistry, 2009 , # 11 p. 1514 - 1520
反应条件
lithium aluminium tetrahydride
1.) THF, room temperature; Multistep reaction. Title compound not separated from byproducts;
参考文献
Huggins, John M.; Bergman, Robert G.
Journal of the American Chemical Society, 1981 , vol. 103, # 11 p. 3002 - 3011
反应条件
di-tert-butyl peroxide
T=140 - 150°C; 3.5 h;
参考文献
Abramovici,M.; Pines,H.
Journal of Organic Chemistry, 1969 , vol. 34, p. 266 - 270
反应条件
in tetrahydrofuran
T=25°C; 2 h; Title compound not separated from byproducts;
参考文献
Jeganathan, Suruliappa; Tsukamoto, Masamitsu; Schlosser, Manfred
Synthesis, 1990 , # 2 p. 109 - 111
反应条件
in tetrahydrofuran
T=25°C; Product distribution;
参考文献
Schlosser, Manfred; Schlaub, Bruno
Journal of the American Chemical Society, 1982 , vol. 104, # 21 p. 5821 - 5823
参考文献
Vedejs, E.; Meier, G. P.; Snoble, K. A. J.
Journal of the American Chemical Society, 1981 , vol. 103, # 10 p. 2823 - 2831
反应条件
hydrogen; silica gel; rhodium
Product distributionMechanism;
参考文献
Leconte, M.; Theolier, A.; Rojas, D.; Basset, J. M.
Journal of the American Chemical Society, 1984 , vol. 106, # 4 p. 1141 - 1142
反应条件
in tetrahydrofuran
T=25°C; Product distribution;
参考文献
Schlosser, Manfred; Schlaub, Bruno
Journal of the American Chemical Society, 1982 , vol. 104, # 21 p. 5821 - 5823
参考文献
Mitchell, Terence N.; Reimann, Werner
Journal of Organometallic Chemistry, 1985 , vol. 281, p. 163 - 172
