in diethyl ether; dichloromethane T=-10 - 18°C;

暂无反应条件数据

1: butyllithium, diisopropylamine / tetrahydrofuran / 0.5 h / 0 °C 2: CuBr*SMe2 / 1.) THF, 1.5 h, -78 deg C; 2.) 30 min, 0 deg C; View Scheme

1: benzene / 11 h / Irradiation 2: 82 percent / diethyl ether / -25 °C 3: 85 percent / pyridine, CrO3 / CH2Cl2 View Scheme

1: 82 percent / diethyl ether / -25 °C 2: 85 percent / pyridine, CrO3 / CH2Cl2 View Scheme

1.1: 49 percent / selenium dioxide on silica gel; t-butylhydroperoxide / CH2Cl2; various solvent(s) / 48 h / 18 °C 2.1: 2-methyl-2-butene; sodium dihydrogen phosphate monohydrate / 2-methyl-propan-2-ol; H2O; tetrahydrofuran / 0.2 h / 18 °C 2.2: 87 percent / sodium chlorite / 2-methyl-propan-2-ol; H2O; tetrahydrofuran / 20 h / 0 - 18 °C 3.1: 95 percent / CH2Cl2; diethyl ether / -10 - 18 °C View Scheme

1.1: 2-methyl-2-butene; sodium dihydrogen phosphate monohydrate / 2-methyl-propan-2-ol; H2O; tetrahydrofuran / 0.2 h / 18 °C 1.2: 87 percent / sodium chlorite / 2-methyl-propan-2-ol; H2O; tetrahydrofuran / 20 h / 0 - 18 °C 2.1: 95 percent / CH2Cl2; diethyl ether / -10 - 18 °C View Scheme