in neat (no solvent)
byproducts: ClO2, Cl2O7; prepn. by interaction of ozone (initial pressure was 1.0 torr) with chlorinated methanes adsorbed on a thin ice film over the temperature range 210-292 K; not isolated; monitored by IR spectroscopy;
参考文献
Vysokikh; Mukhamedzyanova; Yagodovskaya; Savilov; Lunin
Russian Journal of Physical Chemistry A, 2007 , vol. 81, # 11 p. 1836 - 1839
n-BuLi in dichloromethane
(N2); CH2Cl2 was added to B compd. at -78°C; soln. of n-BuLi in hexane was added; mixt. was stirred at -78°C for 4 h and at 25°C for 2 h; solvent removed; chromd. (silica gel, pentane); elem. anal.;
参考文献
Fang, Xiangdong; Yang, Hong; Kampf, Jeff W.; Holl, Mark M. Banaszak; Ashe III, Arthur J.
Organometallics, 2006 , vol. 25, # 2 p. 513 - 518
