in neat (no solvent) Kinetics; byproducts: CO2, CaCO3; TCB mixed with CaO at 1:12 molar ratio; planetary ball mill; mixt. put in zirconia pot; grinding operated at 700 rpm in air or Ar; millig stopped 15 min for every 15 min of grinding; detd. by XRD; ESR, FTIR and Raman spectra;
参考文献
Journal of Physical Chemistry B, , vol. 107, # 40 p. 11091 - 11097
in neat (no solvent) 200 - 420°C, decompn. of Na2C2O4 to Na2CO3 and CO, disproportionation of some CO to CO2 and C, the composition of the products is depending on the temperature;;
参考文献
Proceedings of the Chemical Society, London, , vol. 20, p. 156 - 156
in carbon dioxide byproducts: CaCO3; High Pressure; stainless steel autoclave, 500-600 °C for 24 h; solid was collected, rinsed with ethanol, washing with 6.0 M aq. HCl;
参考文献
Chemical Physics Letters, , vol. 421, # 4-6 p. 584 - 588
