in neat (no solvent, solid phase) Zr5Sb3.0 and various amounts of Sb sealed in Ta container, heated in vac. furnace (ca. 1E-5 Torr, 1300 ° C, 3 d), ZrO2 formed because of inadequate vac.; ZrSb(1-x) detected by powder diffraction;
参考文献
Garcia, Eduardo; Corbett, John D.
Inorganic Chemistry, 1988 , vol. 27, p. 2353 - 2359
in neat (no solvent, solid phase) elements and small quantity of SbI3 sealed in Ta container, heated in evacuated mullite tube (1300 ° C, 2 wks), vac. not adequate to maintain compositional integrity;
参考文献
Garcia, Eduardo; Corbett, John D.
Inorganic Chemistry, 1988 , vol. 27, p. 2353 - 2359
