in neat (no solvent) byproducts: SiO2, H2O; slow decomposition of dioxodisiloxane at room temp., accelerated at higher temp.;; formation of amorphous Si;;
in gaseous matrix byproducts: H2; other Radiation; photolysis of pure SiH4 or a 37percent mixture with N2 or Ar or H2 or He (total pressure = 80 Torr) in stainless steel cell by cw CO2 laser (945.98 cm**-1=IR), strong luminescence accompanies the react.; traces of higher silanes (gases) and solid hydrogenated silicon also present, H2 or He inhibit the react.;
参考文献
Chemical Physics Letters, , vol. 154, p. 217 - 222
