2-乙炔-1,4-二甲基苯合成路线 (共 6 条)
反应条件
18-crown-6 ether; potassium tert-butylate
参考文献
Apeloig, Yitzhak; Franke, Wilfried; Rappoport, Zvi; Schwarz, Helmut; Stahl, Daniel
Journal of the American Chemical Society, 1981 , vol. 103, # 10 p. 2770 - 2780
反应条件
potassium tert-butylate in dimethyl sulfoxide
参考文献
Yates, Keith; Mandrapilias, George
Journal of Organic Chemistry, 1980 , vol. 45, # 19 p. 3902 - 3906
反应条件
1: 1.) Br2, 2.) KOBu-t 2: 94 percent / KOBu-t, 18-crown-6 ether View Scheme
参考文献
Journal of the American Chemical Society, , vol. 103, # 10 p. 2770 - 2780
反应条件
1: 39 percent / Mg / diethyl ether / 2 h / Heating 2: 71 percent / n-butyllithium / diethyl ether / 0.5 h / -50 °C / Heating View Scheme
参考文献
Journal of Fluorine Chemistry, , vol. 43, p. 35 - 52
反应条件
[(PPh3)3Pd] in tetrahydrofuran T=22°C; 48 h; other reagent, reaction time; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 62, # 25 p. 8957 - 8960
反应条件
(i) PCl5, (ii) NaNH2, liq. NH3; Multistep reaction;
参考文献
Journal of Organic Chemistry, , vol. 25, p. 687 - 690