1: tBuCH2CH2B(H)NiPr2; 4-Iodobenzenediazonium tetrafluoroborate With Schwartz's reagent in acetonitrile T=20°C; 2.5 h; 2: With methanol in acetonitrile T=0 - 20°C; 1 h; 3: 2,3-dimethylbutane-2,3-diol in diethyl ether; acetonitrile T=20°C; 4 h; Reagent/catalyst;
参考文献
UNIVERSITE DE BORDEAUX 1; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; PUCHEAULT, Mathieu Jonathan Damien; MARCIASINI, Ludovic Daniel Alain; VAULTIER, Michel
Patent: WO2014/9169 A1, 2014 ;
Location in patent: Page/Page column 53-54; 69 ;
copper(l) iodide; tributylphosphine; potassium tert-butylate in tetrahydrofuran byproducts: KI, C6H5Bpin; react. of (B(OC(CH3)2)2)2 (1 equiv.), 1,4-I2C6H4 (1 equiv.), CuI (10 molpercent), nBu3P (13 molpercent) and KOtBu (1.5 equiv.) at room temp.; detd. by XRD;
参考文献
Angewandte Chemie, International Edition, , vol. 48, p. 5350 - 5354
Angewandte Chemie, , vol. 121, p. 5454 - 5458
