1-烯丙基环己烷羰基氯化物合成路线 （共 5 条）
反应条件
1: 72 percent / iPr2NLi / tetrahydrofuran / 2 h / -78 °C
2: 92 percent / 15percent ethanolic KOH / 48 h / Heating
3: sodium, oxalyl chloride / diethyl ether / 3 h / Heating
View Scheme
参考文献
Nuhrich, A.; Moulines, J.
Tetrahedron, 1991 , vol. 47, # 18 p. 3075 - 3088
反应条件
1: 92 percent / 15percent ethanolic KOH / 48 h / Heating
2: sodium, oxalyl chloride / diethyl ether / 3 h / Heating
View Scheme
参考文献
Nuhrich, A.; Moulines, J.
Tetrahedron, 1991 , vol. 47, # 18 p. 3075 - 3088
反应条件
1: lithium diisopropylamide / 1.) THF, 0 deg C, then 25 deg C, 1 h and 60 deg C, 0.5 h, 2.) 0 deg C, then 25 deg C, 16 h
2: thionyl chloride / 1 h / 25 °C
View Scheme
参考文献
Miller, R. D.; Goelitz, P.
Journal of Organic Chemistry, 1981 , vol. 46, # 8 p. 1616 - 1618
反应条件
aluminium trichloride
Yield given;
参考文献
Nakamura, Eiichi; Fukuzaki, Kentaro; Kuwajima, Isao
Journal of the Chemical Society, Chemical Communications, 1983 , # 9 p. 499 - 501
反应条件
1: ammonia / diethyl ether / ice-cooling
2: 83 percent / LiAlH4 / tetrahydrofuran / 2.5 h / Heating
View Scheme
参考文献
Nuhrich, A.; Moulines, J.
Tetrahedron, 1991 , vol. 47, # 18 p. 3075 - 3088
