alpha-乙烯基苄基乙酸酯合成路线 （共 52 条）
反应条件
air; palladium diacetate; silver carbonate in benzene
Heck reaction; 15 h; Reflux; stereoselective reaction;
参考文献
Pan, Delin; Chen, Anjun; Su, Yijin; Zhou, Wang; Li, Si; Jia, Wei; Xiao, Juan; Liu, Qingjian; Zhang, Liangren; Jiao, Ning
Angewandte Chemie - International Edition, 2008 , vol. 47, # 25 p. 4729 - 4732
反应条件
CuF2; potassium hydrogen difluoride; silver(I) acetate; palladium diacetate in acetone
T=85°C; Heck reaction; 5 h; chemoselective reaction;
参考文献
Su, Yijin; Jiao, Ning
Organic Letters, 2009 , vol. 11, # 14 p. 2980 - 2983
反应条件
(R)-(+)-2-(Diphenylphosphino)-2′-methoxy-1,1′-binaphthyl; bis(η3-allyl-μ-chloropalladium(II)); sodium hydride
1.) THF, 2.) THF, 20 deg C, 12 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Vyskocil, Stepan; Smrcina, Martin; Hanus, Vladimir; Polasek, Miroslav; Kocovsky, Pavel
Journal of Organic Chemistry, 1998 , vol. 63, # 22 p. 7738 - 7748
反应条件
bis(η3-allyl-μ-chloropalladium(II)); triphenylphosphine in tetrahydrofuran
T=0°C; 12 h; other catalyst, temperature, time; also in the presence of various alkali metal halides; also with other nucleofiles; Product distribution;
参考文献
Kawatsura, Motoi; Uozumi, Yasuhiro; Hayashi, Tamio
Chemical Communications, 1998 , # 2 p. 217 - 218
反应条件
1: bis(dimethylphenylsilyl)zinc With copper(l) iodide in tetrahydrofuran
T=0°C; 0.333333 h;
2: rac-α-vinyl benzylacetate in tetrahydrofuran
T=0°C; Title compound not separated from byproducts;
参考文献
Oestreich, Martin; Auer, Gertrud
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 5 p. 637 - 640
反应条件
anhydrous magnesium perchlorate; [Ir(η2-ethylene)2Cl]2; sodium perchlorate; (1S,4R,8R)-8-methoxy-1,8-dimethyl-2-phenylbicyclo[2.2.2]octa-2,5-diene in 1,4-dioxane; water
T=23 - 25°C; 40 h; Inert atmosphere; stereoselective reaction;
参考文献
Fournier, Pierre; Fiammengo, Roberto; Jaeschke, Andres
Angewandte Chemie, International Edition, 2009 , vol. 48, p. 4426 - 4429
Angewandte Chemie, 2009 , vol. 121, p. 4490 - 4493
反应条件
ruthenium trichloride; 2,6-bis[(4S)-isopropyl-2-oxazolin-2-yl]pyridine in tetrahydrofuran
T=60°C; 24 h; Inert atmosphere;
参考文献
Kawatsura, Motoi; Uchida, Kenta; Terasaki, Shou; Tsuji, Hiroaki; Minakawa, Maki; Itoh, Toshiyuki
Organic Letters, 2014 , vol. 16, # 5 p. 1470 - 1473
反应条件
lithium chloride; bis(dibenzylideneacetone)-palladium(0) in N,N-dimethyl-formamide
T=56°C; 47 h;
参考文献
Valle, L. Del; Stille, J. K.; Hegedus, L. S.
Journal of Organic Chemistry, 1990 , vol. 55, p. 3019 - 3023
反应条件
tetraethylammonium p-toluenesulfonate; tetrakis(triphenylphosphine) palladium(0) in acetonitrile
Electrochemical reaction, Pb cathode, Pt anode;
参考文献
Torii, Sigeru; Tanaka, Hideo; Katoh, Tetsuo; Morisaki, Kazuo
Tetrahedron Letters, 1984 , vol. 25, # 30 p. 3207 - 3208
反应条件
lithium chloride; bis(dibenzylideneacetone)-palladium(0) in N,N-dimethyl-formamide
12 h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tsuji, Yasushi; Kajita, Satoshi; Isobe, Shinya; Funato, Masahiro
Journal of Organic Chemistry, 1993 , vol. 58, # 14 p. 3607 - 3608
