sodium hypobromide in 1,4-dioxane

1,4-diaza-bicyclo[2.2.2]octane; potassium carbonate; palladium diacetate in acetone T=110°C; Suzuki-Miyaura cross-coupling reaction; 3.5 h;

Pd(OH)2/Fe3O4; sodium carbonate in toluene T=130°C; Suzuki-Miyaura reaction; 24 h;

potassium phosphate; trans-bis((o-trifluoromethylphenyl)tert-butylmethylphosphine)palladiumdichloride in toluene T=90°C; Suzuki-Miyaura coupling; Inert atmosphere;

aluminium trichloride in dichloromethane T=0°C; 6 h;

potassium carbonate; polyurea encapsulated Pd(OAc)2 in ethanol; toluene T=80°C;

potassium phosphate; triphenylphosphine; palladium diacetate in N,N-dimethyl-formamide T=90°C; 1 h;

N-ethyl-N,N-diisopropylamine; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct in water; isopropyl alcohol T=100°C; Suzuki coupling; 0.166667 h; microwave irradiation;

1: (4-fluoro-phenyl)-magnesium bromide With lithium chlorozincate in tetrahydrofuran T=25°C; 0.5 h; Inert atmosphere; 2: With 2-iodo-propane in tetrahydrofuran T=25°C; 5 h; Inert atmosphere; 3: para-bromoacetophenone With bis(dibenzylideneacetone)-palladium(0); dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine in tetrahydrofuran T=25°C; Negishi cross-coupling reaction; 0.0833333 h; Inert atmosphere;

potassium phosphate; triphenylphosphine; palladium diacetate in N,N-dimethyl-formamide T=90°C; 1 h;