1.1: 86 percent / LiAlH4 / diethyl ether / 20 h 2.1: 62 percent / pyridinium chlorochromate / CH2Cl2 / 20 h / 20 °C 3.1: NH4Cl; aq. NH3 / ethanol / 24 h / 20 °C 3.2: 32 percent / aq. HCl / ethanol / 6 h / Heating View Scheme
参考文献
Nestl, Bettina M.; Glueck, Silvia M.; Hall, Melanie; Kroutil, Wolfgang; Stuermer, Rainer; Hauer, Bernhard; Faber, Kurt
European Journal of Organic Chemistry, 2006 , # 20 p. 4573 - 4577
lithium aluminium tetrahydride in diethyl ether 20 h;
参考文献
Nestl, Bettina M.; Glueck, Silvia M.; Hall, Melanie; Kroutil, Wolfgang; Stuermer, Rainer; Hauer, Bernhard; Faber, Kurt
European Journal of Organic Chemistry, 2006 , # 20 p. 4573 - 4577
1: 86 percent / LiAlH4 / diethyl ether / 20 h 2: 62 percent / pyridinium chlorochromate / CH2Cl2 / 20 h / 20 °C View Scheme
参考文献
Nestl, Bettina M.; Glueck, Silvia M.; Hall, Melanie; Kroutil, Wolfgang; Stuermer, Rainer; Hauer, Bernhard; Faber, Kurt
European Journal of Organic Chemistry, 2006 , # 20 p. 4573 - 4577
hydrogen; palladium on activated charcoal in ethyl acetate
P=750.06 Torr;
参考文献
Nestl, Bettina M.; Glueck, Silvia M.; Hall, Melanie; Kroutil, Wolfgang; Stuermer, Rainer; Hauer, Bernhard; Faber, Kurt
European Journal of Organic Chemistry, 2006 , # 20 p. 4573 - 4577
Novozym 435; acylase I from Aspergillus melleus; amano lipase AK from pseudomonas fluorescens; lipase from wheat germ; papaine in toluene
T=40°C; 48 h; Enzymatic reaction; Mechanism;
参考文献
Zysk, Malgorzata; Zadlo, Anna; Brodzka, Anna; Wisniewska, Catalina; Ostaszewski, Ryszard
Journal of Molecular Catalysis B: Enzymatic, 2014 , vol. 102, p. 225 - 229
1,2-bis(di-tert-butylphosphino)benzene; methanesulfonic acid; palladium diacetate in toluene
P=4560 Torr; 12 h; Heating; Title compound not separated from byproducts;
