catalyst: TiO2 or platinized TiO2Pt in water
Kinetics; byproducts: H2O, O2; Irradiation (UV/VIS); in quartz vessel, with reflux condenser, bubbling O2, mixing; not sepd., detd. electrochemically;
参考文献
Kogo, Katsuyuki; Yoneyama, Hiroshi; Tamura, Hideo
Journal of Physical Chemistry, 1980 , vol. 84, # 13 p. 1705 - 1710
sulfur dioxide in neat (no solvent)
Kinetics; electronresonance;
参考文献
Dillard, J. G.; Franklin, J. L.; Seitz, W. A.
Journal of Chemical Physics, 1968 , vol. 48, p. 3828 - 3829
Show Details
Gmelin Handbook: C: MVol.D3, 6.2.4.7.4, page 205 - 205
sodium hydroxide in water
Kinetics; byproducts: CO3(2-); basic hydrolysis of cyanogen bromide at room temp.; products are identified by (13)C-NMR-spectroscopy, monitored by membrane introduction mass spectrometry;
参考文献
Gerritsen, Cynthia M.; Gazda, Michael; Margerum, Dale W.
Inorganic Chemistry, 1993 , vol. 32, p. 5739 - 5748
catalyst Pd/Al2O3 in neat (no solvent)
byproducts: H(1+); exposing a Pd/Al2O3 catalyst to 15 Torr of a CO/NH3 mixt. (2:1) at 298 K for 30 min; detd. by IR spectroscopy;
参考文献
Paul, D. K.; Worley, S. D.
Journal of Physical Chemistry, 1990 , vol. 94, # 26 p. 8956 - 8959
