[(三氟甲基)亚磺酰]苯合成路线 （共 14 条）
反应条件
phosphorus pentachloride
参考文献
Yagupol'skii,L.M. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1965 , vol. 35, # 2 p. 377 - 387,377 - 385
反应条件
1: chloro-trimethyl-silane With magnesium in N,N-dimethyl-formamide T=0°C; 0.0333333 h; 2: PhSOCF3 in N,N-dimethyl-formamide T=0 - 20°C; 2 h;
参考文献
Prakash, G.K. Surya; Hu, Jinbo; Olah, George A.
Journal of Organic Chemistry, 2003 , vol. 68, # 11 p. 4457 - 4463
反应条件
1: With trifluoromethylsulfonic anhydride T=20 - 50°C; 2: With water
参考文献
European Journal of Organic Chemistry, , # 31 p. 5313 - 5316
反应条件
magnesium in N,N-dimethyl-formamide T=20°C; 0.5 h;
参考文献
Journal of Organic Chemistry, , vol. 68, # 11 p. 4457 - 4463
反应条件
[bmim]BF4; trichloroisocyanuric acid; water
T=20°C; 0.166667 h;
参考文献
Tang, Ri-Yuan; Zhong, Ping; Lin, Qiu-Lian
Journal of Fluorine Chemistry, 2007 , vol. 128, # 6 p. 636 - 640
反应条件
cesium fluoride in neat (no solvent)
T=100°C; 6 h;
参考文献
Singh, Rajendra P.; Cao, Ganfeng; Kirchmeier, Robert L.; Shreeve, Jean'ne M.
Journal of Organic Chemistry, 1999 , vol. 64, # 8 p. 2873 - 2876
反应条件
trifluorormethanesulfonic acid
T=20°C; 24 h;
参考文献
Magnier, Emmanuel; Blazejewski, Jean-Claude; Tordeux, Marc; Wakselman, Claude
Angewandte Chemie - International Edition, 2006 , vol. 45, # 8 p. 1279 - 1282
反应条件
tris(dimethylamino)-sulphonium difluorotrimethylsilicate in tetrahydrofuran
30 min at -25 deg C, then slowly warmed up to 10 deg C (total time 2 h);
参考文献
Movchun, Valeria N.; Kolomeitsev, Alexander A.; Yagupolskii, Yurii L.
Journal of Fluorine Chemistry, 1995 , vol. 70, # 2 p. 255 - 258
反应条件
3-chloro-benzenecarboperoxoic acid in dichloromethane
1.) 0 deg C, 10 h, 2.) room temperature, 1 h;
参考文献
Yang, Jing-Jing; Kirchmeier, Robert L.; Shreeve, Jean'ne M.
Journal of Organic Chemistry, 1998 , vol. 63, # 8 p. 2656 - 2660
反应条件
1: 65 percent / N-methylpyrrolidone
2: 90 percent / m-chloroperbenzoic acid / CH2Cl2 / 1.) 0 deg C, 10 h, 2.) room temperature, 1 h
View Scheme
参考文献
Yang, Jing-Jing; Kirchmeier, Robert L.; Shreeve, Jean'ne M.
Journal of Organic Chemistry, 1998 , vol. 63, # 8 p. 2656 - 2660
