1-溴-3-氯-2-甲基丙烷合成路线 （共 12 条）
反应条件
hydrogen bromide; dibenzoyl peroxide
参考文献
Chemische Berichte, , vol. 91, p. 2130,2140
Journal of the American Chemical Society, , vol. 75, p. 3344,3347
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 47,54
Chem.Abstr., , p. 4491
反应条件
(i) O2, (ii) HBr; Multistep reaction;
参考文献
Journal of Heterocyclic Chemistry, , vol. 8, p. 961 - 966
参考文献
Industrial and Engineering Chemistry, , vol. 33, p. 385
反应条件
sodium ethanolate in ethanol T=80 - 85°C; 14 h;
参考文献
BOEHRINGER INGELHEIM INTERNATIONAL GMBH; BROCHU, Christian; GRAND-MAÎTRE, Chantal; JOLY, Marc-André; KUHN, Cyrille; BERTRAND-LAPERLE, Mégan; PESANT, Marc
Patent: WO2013/26162 A1, 2013 ;
Location in patent: Page/Page column 40 ;
参考文献
Morren
Ind. chim. belge, Sonderband, vol. 31, p. Congr. int. Chim. ind. Luettich 1958, Bd. 2, S. 447
反应条件
(i) NaOEt, (ii) (hydrolysis), (iii) (decarboxylation); Multistep reaction;
参考文献
Conia,J.-M.; Gore,J.
Bulletin de la Societe Chimique de France, 1963 , p. 735 - 743
反应条件
in tetrahydrofuran under N2: dropwise addn. of a THF soln. of 10.11 mmol Na(Mn(CO)5) with stirring to 5.103 mmol 1-bromo-3-chloro-2-methylpropane; heating for 2 h at reflux; removing solvent under reduced pressure;; extraction of oil with hexane; chromy. (alumina, hexane): first band is (Mn2(CO)19), second band is MnMn-compound; recrystallization from hexane at -15°C; elem. anal.;;
参考文献
Andersen, Jo-Ann M.; Archer, Stephen J.; Moss, John R.; Niven, Margaret L.
Inorganica Chimica Acta, 1993 , vol. 206, p. 187 - 192
参考文献
Silver,M.S. et al.
Journal of the American Chemical Society, 1961 , vol. 83, p. 3671 - 3678
反应条件
(i) NaNH2, Na2O2, liq. NH3, (ii) /BRN= 102555/, NaI; Multistep reaction;
参考文献
Ratouis,R.; Boissier,J.R.
Bulletin de la Societe Chimique de France, 1966 , p. 2963 - 2965
参考文献
Bourquin et al.
Helvetica Chimica Acta, 1958 , vol. 41, p. 1072,1080
