反式-巴豆基硼酸频哪醇酯合成路线 （共 22 条）
反应条件
[Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane in 1,2-dichloro-ethane T=90°C; 6 h; Inert atmosphere; optical yield given as percent de;
参考文献
Shimizu, Hiroshi; Igarashi, Tomohiro; Miura, Tomoya; Murakami, Masahiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 48 p. 11465 - 11469
反应条件
1: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere 2: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere 3: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere View Scheme
参考文献
Shimizu, Hiroshi; Igarashi, Tomohiro; Miura, Tomoya; Murakami, Masahiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 48 p. 11465 - 11469
反应条件
1: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere 2: [Rh(nbd)(CH3CN)2]SbF6; bis(1,1-diphenylphosphino)methane / 1,2-dichloro-ethane / 6 h / 90 °C / Inert atmosphere View Scheme
参考文献
Shimizu, Hiroshi; Igarashi, Tomohiro; Miura, Tomoya; Murakami, Masahiro
Angewandte Chemie - International Edition, 2011 , vol. 50, # 48 p. 11465 - 11469
反应条件
1: With [Cu(N,N′-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene)Cl]; potassium tert-butylate in tetrahydrofuran T=70°C; 16 h; Inert atmosphereSealed tube; 2: With hydrogenchloride in tetrahydrofuran Inert atmosphereSealed tube; regioselective reaction;
参考文献
Organic Letters, , vol. 15, # 15 p. 4034 - 4037
反应条件
in tetrahydrofuran 60 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Niel, Gilles; Roux, Florence; Maisonnasse, Ysadora; Maugras, Isabelle; Poncet, Joel; Jouin, Patrick
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 10 p. 1275 - 1280
反应条件
[Ni0(1,5-cyclooctadiene)2]; tri-cyclo-hexyl-phosphine in ethyl acetate
T=60°C; 12 h; Inert atmosphere; stereoselective reaction;
参考文献
Zhang, Ping; Roundtree, Ian A.; Morken, James P.
Organic Letters, 2012 , vol. 14, # 6 p. 1416 - 1419
反应条件
[Pd(CH3CN)(C6H3(CH2SCH3)2)](1+)*BF4(1-)=[Pd(CH3CN)(C6H3(CH2SCH3)2)]BF4 in chloroform
T=50°C; 16 h;
参考文献
Selander, Nicklas; Szabo, Kalman J.
Journal of Organic Chemistry, 2009 , vol. 74, # 15 p. 5695 - 5698
反应条件
n-butyllithium; potassium tert-butylate in tetrahydrofuran; hexane; dichloromethane
soln. of (E)-2-butene (64.6 mmol,THF) was treated with KO-t-Bu (58.9 mmol) and n-BuLi (58.9 mmol) (hexane, -78°C, Ar); heating to -50°C for 15 min, recooling; addn. of FB(OMe)2 (74 mmol) and pinacol (66.8 mmol) in CH2Cl2; mixt. was concd. in vacuo, distn. at 68-76°C (7 mm Hg) gave product (96percent isomeric purity);
参考文献
Roush,W.R.; Adam,M.A.; Walts,A.E.
Journal of the American Chemical Society, 1986 , vol. 108, p. 3422
反应条件
[Pt(dba)2]; triphenyl-arsane; triethylamine in toluene
T=50°C; borylation; 16 h;
参考文献
Murata, Miki; Watanabe, Shinji; Masuda, Yuzuru
Tetrahedron Letters, 2000 , vol. 41, # 31 p. 5877 - 5880
反应条件
[Pt(dba)2]; triphenyl-arsane; triethylamine in toluene
T=50°C; borylation; 16 h;
参考文献
Murata, Miki; Watanabe, Shinji; Masuda, Yuzuru
Tetrahedron Letters, 2000 , vol. 41, # 31 p. 5877 - 5880
