3-甲基-2-(3-甲基丁-2-烯基)丁烷-1,3-二醇合成路线 （共 10 条）
反应条件
potassium hydrogensulfate T=65 - 70°C; P=1 Torr; destillation;
参考文献
Babin, Didier; Fourneron, Jean-Dominique; Julia, Marc
Bulletin de la Societe Chimique de France, 1980 , vol. 2, # 11-12 p. 588 - 600
反应条件
potassium fluoride; water; dihydrogen peroxide; potassium hydrogencarbonate in tetrahydrofuran; methanol
0.333333 h; Ambient temperature;
参考文献
Fleming, Ian; Lee, Duckhee
Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 17 p. 2701 - 2709
反应条件
3: 80 percent / diethyl ether; tetrahydrofuran / 24 h / Ambient temperature
4: 80 percent / HCl, MeOH / CH2Cl2 / 0.02 h / Ambient temperature
5: 70 percent / H2O2, H2O, KF, KHCO3 / tetrahydrofuran; methanol / 0.33 h / Ambient temperature
View Scheme
参考文献
Fleming, Ian; Lee, Duckhee
Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 17 p. 2701 - 2709
反应条件
2: 80 percent / diethyl ether; tetrahydrofuran / 24 h / Ambient temperature
3: 80 percent / HCl, MeOH / CH2Cl2 / 0.02 h / Ambient temperature
4: 70 percent / H2O2, H2O, KF, KHCO3 / tetrahydrofuran; methanol / 0.33 h / Ambient temperature
View Scheme
参考文献
Fleming, Ian; Lee, Duckhee
Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 17 p. 2701 - 2709
反应条件
diethyl ether
T=-15°C;
参考文献
Schinz; Schaeppi
Helvetica Chimica Acta, 1947 , vol. 30, p. 1493
反应条件
1: 80 percent / HCl, MeOH / CH2Cl2 / 0.02 h / Ambient temperature
2: 70 percent / H2O2, H2O, KF, KHCO3 / tetrahydrofuran; methanol / 0.33 h / Ambient temperature
View Scheme
参考文献
Fleming, Ian; Lee, Duckhee
Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 17 p. 2701 - 2709
反应条件
1: 80 percent / diethyl ether; tetrahydrofuran / 24 h / Ambient temperature
2: 80 percent / HCl, MeOH / CH2Cl2 / 0.02 h / Ambient temperature
3: 70 percent / H2O2, H2O, KF, KHCO3 / tetrahydrofuran; methanol / 0.33 h / Ambient temperature
View Scheme
参考文献
Fleming, Ian; Lee, Duckhee
Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 17 p. 2701 - 2709
反应条件
1: Ba(OH)2; ethanol
2: diethyl ether / -15 °C
View Scheme
参考文献
Schinz; Schaeppi
Helvetica Chimica Acta, 1947 , vol. 30, p. 1493
反应条件
potassium carbonate
1.) 45 min, RT 2.) methanol, water, RT; Yield given. Multistep reaction;
参考文献
Babin, Didier; Fourneron, Jean-Dominique; Julia, Marc
Bulletin de la Societe Chimique de France, 1980 , vol. 2, # 11-12 p. 588 - 600
参考文献
Schinz; Schaeppi
Helvetica Chimica Acta, 1947 , vol. 30, p. 1493
Full Text Show Details
Ruzicka; Roethlisberger
Helvetica Chimica Acta, 1935 , vol. 18, p. 441
