1,1,3,3,3-五氟-1-丙烯合成路线 (共 64 条)
反应条件
T=24.9°C; kinetic data for the reaction; Rate constant;
参考文献
Journal of the American Chemical Society, , vol. 109, # 24 p. 7334 - 7340
反应条件
T=24.9°C; kinetic data for the reaction with other ROH molecules; Rate constant;
参考文献
Journal of the American Chemical Society, , vol. 109, # 24 p. 7334 - 7340
参考文献
Journal of the American Chemical Society, , vol. 70, p. 2023
反应条件
T=25°C; P=14 Torr; 1.5 h; Product distribution;
参考文献
Journal of Physical Chemistry, , vol. 92, # 13 p. 3818 - 3820
反应条件
T=25°C; P=14 Torr; 1.5 h; Product distribution;
参考文献
Journal of Physical Chemistry, , vol. 92, # 13 p. 3818 - 3820
反应条件
T=21.85°C; substituent effects on the disproportionation/combination rate constant ratio; Rate constant;
参考文献
International Journal of Chemical Kinetics, , vol. 31, # 2-3 p. 237 - 243
反应条件
hydrogen; palladium on activated charcoal T=180°C; P=7600.51 Torr; Industry scale;
参考文献
HONEYWELL INTERNATIONAL INC.
Patent: WO2002/6194 A2, 2002 ;
Location in patent: Page 18 ;
反应条件
hydrogen; palladium/alumina
参考文献
Knunyants,I.L. et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1960 , p. 1312 - 1317
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1960 , p. 1412 - 1418
反应条件
byproducts: H2; Irradiation (UV/VIS); 12 d: no addn. of (CF3)2PH to CF3CHCF2, main amt. of educts unchanged; additional formn. of 13 percent polyphosphanes and yellow inflammable ppt.; yiled of H2: 12 percent;
参考文献
Fields,R. et al.
Journal of the Chemical Society [Section] C: Organic, 1970 , p. 1370 - 1375
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Gmelin Handbook: F: PerFHalOrg.3, 1.2, page 14 - 30
反应条件
bromine; tert.-butyl lithium; zinc(II) chloride 1.) Et2O, pentane, -78 deg C 30 min; THF, -78 deg C, 1 h, 2.) triglyme; Yield given. Multistep reaction;
参考文献
Lu, Hengyao; Friedrich, H. Bruce; Burton, Donald J.
Journal of Fluorine Chemistry, 1995 , vol. 75, # 1 p. 83 - 86