tri-tert-butyl phosphine; Ni(acac)2 in tetrahydrofuran
T=20°C; Arylation; 18 h;
参考文献
Boehm, Volker P. W.; Weskamp, Thomas; Gstoettmayr, Christian W. K.; Herrmann, Wolfgang A.
Angewandte Chemie (International Edition in English), 2000 , vol. 39, # 9 p. X1602-1604
Wolfe, John P.; Singer, Robert A.; Yang, Bryant H.; Buchwald, Stephen L.
Journal of the American Chemical Society, 1999 , vol. 121, # 41 p. 9550 - 9561
1: triallyl(4-methylphenyl)silane With tetrabutyl ammonium fluoride in tetrahydrofuran; water
T=20°C; 1 h;
2: 2-Chloro-1,3-dimethylbenzene With 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl; bis(η3-allyl-μ-chloropalladium(II)) in tetrahydrofuran; water
T=80°C; 9 h;