1,3-双(二苯基膦)丙烷合成路线 （共 42 条）
反应条件
lithium in tetrahydrofuran
参考文献
Brooks, Peter; Craig, Donald C.; Gallagher, Michael J.; Rae, A. David; Sarrof, Adrien
Journal of Organometallic Chemistry, 1987 , vol. 323, p. C1 - C4
参考文献
Fochi; Jacopozzi; Wegelius; Rissanen; Cozzini; Marastoni; Fisicaro; Manini; Fokkens; Dalcanale
Journal of the American Chemical Society, 2001 , vol. 123, # 31 p. 7539 - 7552
反应条件
in tetrahydrofuran; ethanol stirring for 2 h; evapn., washing with H2O, drying at 80°C for 12 h;
参考文献
Housecroft, Catherine E.; Shaykh, Bilal A.; Rheingold, Arnold L.; Haggerty, Brian S.
Inorganic Chemistry, 1991 , vol. 30, p. 125 - 130
反应条件
in diethyl ether byproducts: CH3COOH; (Ar), mixed, stirred for 10 min, mixed with DPPPr dropwize with stirring, pptd., stirred for 1 h; filtered, washed with dry ethylether, dried in vac.;
参考文献
Luo, He-Kuan; Kou, Yuan; Wang, Xi-Wen; Li, Da-Gang
Journal of Molecular Catalysis A: Chemical, 2000 , vol. 151, # 1-2 p. 91 - 113
反应条件
in dichloromethane under N2, addn. of complex in CH2Cl2 to soln. of ligand in CH2Cl2, stirred for 25°C for 2 h, white pptn.; evapd. under reduced press., addn. of toluene, heated under reflux for 4 h, pptn., filtered, dried in vac.;
参考文献
Broadwood-Strong, Gillian T. L.; Chaloner, Penny A.; Hitchcock, Peter B.
Polyhedron, 1993 , vol. 12, p. 721 - 730
反应条件
hydrogenchloride; ammonium hydroxide; carbon monoxide; triethylamine; Pd(OAc)2 in methanol; dichloromethane; dimethyl sulfoxide
参考文献
Barrow, James C.; Dorsey, Bruce D.; Selnick, Harold G.; Ngo, Phung L.
Patent: US2002/6923 A1, 2002 ;
US 20020006923 A1
反应条件
in tetrahydrofuran T=50°C; 2 h; Thermodynamic data;
参考文献
Canadian Journal of Chemistry, , vol. 79, # 5-6 p. 626 - 631
反应条件
in tetrahydrofuran (argon); NMR tube: addn. of the ligand to the Pt complex in THF at -78°C, slight warming for dissoln., recooling to -80°C; NMR monitoring;
参考文献
Chaloner, Penny A.; Broadwood-Strong, Gillian T. L.
Journal of the Chemical Society - Dalton Transactions, 1996 , # 6 p. 1039 - 1043
反应条件
in tetrahydrofuran T=50°C; 2 h; Thermodynamic data;
参考文献
Smith D.C.; Cadoret; Jafarpour; Stevens; Nolan
Canadian Journal of Chemistry, 2001 , vol. 79, # 5-6 p. 626 - 631
参考文献
Fochi; Jacopozzi; Wegelius; Rissanen; Cozzini; Marastoni; Fisicaro; Manini; Fokkens; Dalcanale
Journal of the American Chemical Society, 2001 , vol. 123, # 31 p. 7539 - 7552
