3-苯基-1-[4-(三氟甲基)苯基]-1-丙酮合成路线 （共 8 条）
反应条件
[IrH(1,5-cyclooctadiene)Cl(HCN(i-Pr)CHCN(C2H4PPh2))]PF6; potassium hydroxide in toluene T=110°C; 2 h; Inert atmosphere;
参考文献
Gong, Xue; Zhang, Hong; Li, Xingwei
Tetrahedron Letters, 2011 , vol. 52, # 43 p. 5596 - 5600
反应条件
lithium tert-butylate in toluene T=110°C; 12 h; Inert atmosphere;
参考文献
Liang, Yu-Feng; Zhou, Xin-Feng; Tang, Shi-Ya; Huang, Yao-Bing; Feng, Yi-Si; Xu, Hua-Jian
RSC Advances, 2013 , vol. 3, # 21 p. 7739 - 7742
反应条件
potassium phosphate; AlO(OH); palladium in toluene T=110°C; 3 h; Title compound not separated from byproducts;
参考文献
Angewandte Chemie - International Edition, , vol. 44, # 42 p. 6913 - 6915
反应条件
tri-ruthenium(0)dodecacarbonyl in toluene T=140°C; 20 h;
参考文献
Tatamidani, Hiroto; Yokota, Kazuhiko; Kakiuchi, Fumitoshi; Chatani, Naoto
Journal of Organic Chemistry, 2004 , vol. 69, # 17 p. 5615 - 5621
反应条件
pyrrolidine; CataCXium POMetB; bis(dibenzylideneacetone)-palladium(0) in N,N-dimethyl acetamide T=140°C; 4 h; Inert atmosphereMolecular sieve;
参考文献
Colbon, Paul; Ruan, Jiwu; Purdie, Mark; Xiao, Jianliang
Organic Letters, 2010 , vol. 12, # 16 p. 3670 - 3673
反应条件
1: sodium hydroxide / ethanol / 4 h / 0 - 20 °C 2: acetoxy(2,6-bis((diphenylphosphino)methyl)-3,5-dimethylphenyl)palladium(II); butan-1-ol; potassium carbonate / 1 h / |Reflux View Scheme
参考文献
Organic Letters, , vol. 15, # 14 p. 3690 - 3693
反应条件
1: hexane / 6 h / 20 °C / Molecular sieve; Inert atmosphere; UV-irradiation 2: hydrogenchloride; water / tetrahydrofuran / 1 h / 20 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 133, # 11 p. 3716 - 3719
反应条件
1: potassium hydroxide / 16 h / 135 °C / |Inert atmosphere; |Schlenk technique 2: benzaldehyde; potassium hydroxide / 72 h / 160 °C / |Schlenk technique; |Inert atmosphere; |Green chemistry View Scheme
参考文献
Advanced Synthesis and Catalysis, , vol. 355, # 4 p. 697 - 704
