2,2,2-三甲基乙酰苯胺合成路线 （共 72 条）
反应条件
1: triethylamine / dichloromethane / 0 - 20 °C 2: N-benzyl-aniline / N,N-dimethyl-formamide / 144 h / |Glovebox; |UV-irradiation; |Inert atmosphere View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 53, # 2 p. 474 - 478
Angew. Chem., , vol. 126, # 2 p. 484 - 488,5
反应条件
in acetonitrile 2 h; Ambient temperature; Yield given;
参考文献
Journal of Organic Chemistry, , vol. 46, p. 4413 - 4416
反应条件
n-butyllithium; iodine Yield given. Multistep reaction;
参考文献
Tetrahedron Letters, , vol. 30, # 26 p. 3373 - 3376
反应条件
1: pivaloyl 2-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl)sulfide in benzene 2 h; Heating; 2: aniline in benzene cooling; Further stages.;
参考文献
Journal of the Chemical Society. Perkin Transactions 1, , # 10 p. 1271 - 1279
反应条件
(i) Me2NCH2CH2NMe2, Et2O, (ii) O2; Multistep reaction;
参考文献
Journal of Organic Chemistry, , vol. 43, # 4 p. 731 - 734
反应条件
Diphenylketene p-tolylimine in acetonitrile T=30°C; Rate constantKineticsProduct distribution;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 20, p. 2344 - 2348
Zhurnal Organicheskoi Khimii, , vol. 20, # 12 p. 2574 - 2580
反应条件
in acetonitrile-D3 T=30°C; nitrogen, deuterium isotope effects; Mechanism;
参考文献
Journal of Organic Chemistry, , vol. 56, # 19 p. 5716 - 5718
反应条件
(i) NOCl, CHCl3, (ii) /BRN= 605631/, AcOH; Multistep reaction;
参考文献
Journal of the Chemical Society [Section] C: Organic, , p. 1324 - 1328
反应条件
1.) DMF, 70 deg C, 1 h then r.t.; 2.) DMF, 70 deg C, 1 h; Yield given. Multistep reaction;
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 37, # 12 p. 3225 - 3228
反应条件
diethyl ether; methyllithium; tert.-butyl lithium 1.) THF, pentane, -78 deg C, 1 h; 2.) -78 deg C; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Tetrahedron, , vol. 39, # 22 p. 3767 - 3776
