3,4,5-三甲氧基甲苯合成路线 (共 96 条)
反应条件
oxygen; anhydrous cobalt diacetate T=110°C; P=2280 Torr; 2 h; var. catalysts; Product distribution;
参考文献
Kitajima, Nobumasa; Takemura, Kazuya; Moro-Oka, Yoshihiko; Yoshikuni, Tadatsugu; Akada, Mitsuo; et al.
Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 3 p. 1035 - 1038
反应条件
magnesium iodide 2.5 h; neat (no solvent);
参考文献
Bao, Kai; Fan, Aixue; Dai, Yi; Zhang, Liang; Zhang, Weige; Cheng, Maosheng; Yao, Xinsheng
Organic and Biomolecular Chemistry, 2009 , vol. 7, # 24 p. 5084 - 5090
反应条件
oxygen; anhydrous cobalt diacetate T=110°C; P=2280 Torr; 2 h; var. catalysts; Product distribution;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 61, # 3 p. 1035 - 1038
反应条件
potassium permanganate
参考文献
de Laire; Tiemann
Chemische Berichte, 1893 , vol. 26, p. 2019
反应条件
aluminium trichloride in dichloromethane T=25°C; 2 h;
参考文献
Bovicelli, Paolo; Borioni, Giorgio; Fabbrini, Danilo; Barontini, Maurizio
Synthetic Communications, 2008 , vol. 38, # 3 p. 391 - 400
反应条件
trichlorophosphate T=65°C; Vilsmeier-Haack reaction; 5 h;
参考文献
Ji, Yafei; Xu, Wanmei; Jin, Wenhu; Weimin, Yue
Synthetic Communications, 2006 , vol. 36, # 14 p. 1961 - 1965
反应条件
trichlorophosphate T=40 - 80°C;
参考文献
Lu, Liang; Chen, Fener
Synthetic Communications, 2004 , vol. 34, # 22 p. 4049 - 4053
参考文献
Aquila,H.
Justus Liebigs Annalen der Chemie, 1969 , vol. 721, p. 220 - 222
反应条件
boron tribromide in dichloromethane T=0°C; 0.5 h;
参考文献
Tatsuta, Kuniaki; Furuyama, Akiho; Yano, Tomoe; Suzuki, Yasuaki; Ogura, Takashi; Hosokawa, Seijiro
Tetrahedron Letters, 2008 , vol. 49, # 25 p. 4036 - 4039
反应条件
1: 96 percent / 57percent HI, 30percent aq. H3PO2 / Heating
2: 82 percent / molecular sieves 4 Angstroem / Amberlite IR 120-plus / benzene / Heating
3: K2CO3 / Bu4NHSO4 / acetone / 24 h / Heating
4: TsOH / methanol; H2O / 16 h / Ambient temperature
5: 91 percent / K2CO3 / acetone / 15 h / Heating
6: 96 percent / H2 / 10percent Pd/C / tetrahydrofuran / 6 h / Ambient temperature
View Scheme
参考文献
Okamoto; Watanabe; Kawada; Goto; Ashida; Oda; Yajima; Imada; Morimoto
Chemical and pharmaceutical bulletin, 1982 , vol. 30, # 8 p. 2797 - 2819