LiCl in ethanol Electrochem. Process; dry Ar atmosphere; anodic oxidation of Ta in LiCl2 soln.; distillation;
参考文献
Tchebukov; Turova; Korolev; Belokon'
Russian Journal of Inorganic Chemistry, 1997 , vol. 42, # 10 p. 1498 - 1508
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反应条件
in ethanol Electrolysis; anodic dissolution of the metal in anhyd. alcohol in presence of LiCl assupporting electrolite; EtOH was evapd. from resulting electrolyte, the Ta(OEt)5 was extd. from residue with hexane, on prolonged storage of liquid crude Ta(OEt)5 the second Ta-Li complex crystllized in minor yield; elem. anal.;
参考文献
Starikova; Turova; Cheboukov; Yanovsky
Russian Journal of Inorganic Chemistry, 2003 , vol. 48, # 8 p. 1156 - 1162
