1: With aluminum isopropoxide in toluene T=70°C; P=142.514 Torr; 23 h; 2: With methanol; potassium hydroxide; water T=20°C; 0.5 h; Product distribution / selectivity;
参考文献
DSM IP ASSETS B.V.
Patent: WO2005/14509 A1, 2005 ;
Location in patent: Page/Page column 21 ;
[(C4Ph4COHOCC4Ph4)(μ-H)][(CO)4Ru2]; Novozym(R) 435; 2,4-dimethylpentan-3-one in toluene T=70°C; P=142.511 Torr; 40 h; Title compound not separated from byproducts;
参考文献
Verzijl, Gerard K.M.; De Vries, Johannes G.; Broxterman, Quirinus B.
Tetrahedron Asymmetry, 2005 , vol. 16, # 9 p. 1603 - 1610